9-MESITYL-10-METHYLACRIDINIUM PERCHLORATE

Base Information

• Chemical Name: 9-MESITYL-10-METHYLACRIDINIUM PERCHLORATE
• CAS No.: 674783-97-2
• Molecular Formula: C23H22N.ClO4
• Molecular Weight: 411.87808
• Hs Code.: 29339900
• Mol file: 674783-97-2.mol

Synonyms:10-METHYL-9-(2,4,6-TRIMETHYLPHENYL)ACRIDINIUM PERCHLORATE;9-MESITYL-10-METHYLACRIDINIUM PERCHLORATE

Chemical Property of 9-MESITYL-10-METHYLACRIDINIUM PERCHLORATE

Chemical Property:

• PSA: 78.15000
• LogP: 5.62400
• Solubility.: soluble in Acetone

Purity/Quality:

98%,99%, ^*data from raw suppliers

9-Mesityl-10-methylacridinium perchlorate ^*data from reagent suppliers

Safty Information:

• Pictogram(s): O,Xi
• Hazard Codes: O,Xi
• Statements: 8-36/37/38
• Safety Statements: 26

MSDS Files:

SDS file from LookChem

Useful:

• Uses: 9-Mesityl-10-methylacridinium Perchlorate is a photooxygenation catalyst that can be used for various reactions including metal-free ring-opening?metathesis polymerization and?one-pot synthesis of oxazoles from 2H-azirines and aldehydes.

Technology Process of 9-MESITYL-10-METHYLACRIDINIUM PERCHLORATE

There total 9 articles about 9-MESITYL-10-METHYLACRIDINIUM PERCHLORATE which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + 2,4,6-trimethylphenyl bromide (576-83-0) → 9?mesityl-10-methylacridinium perchlorate (674783-97-2)

Guidance literature:

2,4,6-trimethylphenyl bromide; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.55h;

10-methyl-9, 10-dihydro-9-acridinone; In diethyl ether; pentane; at -78 - 25 ℃; for 73h;

With perchloric acid; In ethyl acetate;

DOI:10.1002/anie.201210111

Reference yield: 96.0%

perchloric acid (7601-90-3) + 10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + 2,4,6-trimethylphenyl bromide (576-83-0) → 9?mesityl-10-methylacridinium perchlorate (674783-97-2)

Guidance literature:

2,4,6-trimethylphenyl bromide; With tert.-butyl lithium; In diethyl ether; pentane; at -78 ℃; for 0.5h; Cooling with acetone-dry ice;

10-methyl-9, 10-dihydro-9-acridinone; In diethyl ether; pentane; at -78 - 25 ℃; for 72h; Cooling with acetone-dry ice;

perchloric acid; In ethyl acetate;

DOI:10.1021/ja309635w

Reference yield: 87.0%

10-methyl-9, 10-dihydro-9-acridinone (719-54-0) + 2-mesitylmagnesium bromide (2633-66-1) → 9?mesityl-10-methylacridinium perchlorate (674783-97-2)

Guidance literature:

10-methyl-9, 10-dihydro-9-acridinone; 2-mesitylmagnesium bromide; In tetrahydrofuran;

With sodium hydroxide; In tetrahydrofuran;

DOI:10.1246/bcsj.79.1489

upstream raw materials:

10-methyl-9, 10-dihydro-9-acridinone

2-mesitylmagnesium bromide

perchloric acid

2,4,6-trimethylphenyl bromide

Refernces

• 1、 Tsudaka, Takeshi,Kotani, Hiroaki,Ohkubo, Kei,Nakagawa, Tatsuo,Tkachenko, Nikolai V.,Lemmetyinen, Helge,Fukuzumi, Shunichi. "Photoinduced Electron Transfer in 9-Substituted 10-Methylacridinium Ions". . p. 1306 - 1317. Retrieved 2017.
• 2、 Huang, Xiao-Ying,Ding, Rui,Mo, Zu-Yu,Xu, Yan-Li,Tang, Hai-Tao,Wang, Heng-Shan,Chen, Yan-Yan,Pan, Ying-Ming. "Photocatalytic Construction of S-S and C-S Bonds Promoted by Acridinium Salt: An Unexpected Pathway to Synthesize 1,2,4-Dithiazoles". supporting information. p. 4819 - 4823. Retrieved 2018/08/24.