Platinum--tri(propan-2-yl)phosphane (1/2)

Base Information

Chemical Name:Platinum--tri(propan-2-yl)phosphane (1/2)
CAS No.:60648-71-7
Molecular Formula:C₁₈H₄₂P₂Pt
Molecular Weight:515.559
Hs Code.:
DSSTox Substance ID:DTXSID60578836
Mol file:60648-71-7.mol

Synonyms:DTXSID60578836;Platinum--tri(propan-2-yl)phosphane (1/2)

Suppliers and Price of Platinum--tri(propan-2-yl)phosphane (1/2)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 3 raw suppliers

Chemical Property of Platinum--tri(propan-2-yl)phosphane (1/2)

Chemical Property:

PSA：27.18000
LogP:7.38450
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:6
Exact Mass:515.240970
Heavy Atom Count:21
Complexity:65.7

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)P(C(C)C)C(C)C.CC(C)P(C(C)C)C(C)C.[Pt]

Technology Process of Platinum--tri(propan-2-yl)phosphane (1/2)

There total 5 articles about Platinum--tri(propan-2-yl)phosphane (1/2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

: 59967-54-3,74080-74-3
[(iPr₃P)₂Pt^IICl₂]

: 60648-71-7
[(iPr₃P)₂Pt⁰]

Guidance literature:: With sodium amalgam; In tetrahydrofuran; byproducts: NaCl; under N2 atm. (i-Pr3P)2PtCl2 was dissolved in THF and sodium amalgam wasadded and stirred for 3 days; soln. was filtered and evapd. in vacuo, pentane was added, soln. was filtered and concd. to dryness;
DOI:10.1139/v03-018

Reference yield:

: 81602-78-0
bis(triisopropylphosphine)-3,3-dimethylplatinacyclobutane

: 60648-71-7
[(iPr₃P)₂Pt⁰]

Guidance literature:: With tris(1-methylethyl)phosphine; In cyclohexane; byproducts: 1,1-dimethylcyclopropane, neopentane; heated at 126.5°C in vac.; Kinetics;
DOI:10.1021/ja00377a011

Reference yield:

: 74080-74-3,59967-54-3
trans-dichlorobis(tri-isopropylphosphine)platinum(II)

: 6476-36-4
tris(1-methylethyl)phosphine

: 60648-71-7
[(iPr₃P)₂Pt⁰]

Guidance literature:: With sodium naphthalenide; In tetrahydrofuran; byproducts: NaCl; (Ar, Schlenk) a soln. of sodium naphthalenide in THF was added dropwise to the suspn. of Pt-complex and phosphine in THF, stirred for 2 h; the solvent was removed under vac., an excess of naphthalene was sublimed, the residue was extd. with hexane, filtered;
DOI:10.1021/ja8046238