TETRADECANOIC-D27 ACID

Base Information

• Chemical Name: TETRADECANOIC-D27 ACID
• CAS No.: 60658-41-5
• Molecular Formula: C14HD27O2
• Molecular Weight: 255.54
• Mol file: 60658-41-5.mol

Synonyms:TETRADECANOIC-D27 ACID;MYRISTIC ACID (D27);MYRISTIC-D27 ACID;MYRISTIC-D27 ACID, 98 ATOM % D;Tetradecanoic-d;Tetradecanoic-dacid;Tetradecanoic Acid-D27

Chemical Property of TETRADECANOIC-D27 ACID

Chemical Property:

• Vapor Pressure: 0.000139mmHg at 25°C
• Melting Point: 52-54 °C(lit.)
• Refractive Index: 1.451
• Boiling Point: 250 °C100 mm Hg(lit.)
• Flash Point: >230 °F(lit.)
• PSA: 37.30000
• Density: 1.005g/cm³
• LogP: 4.77210
• Storage Temp.: Refrigerator
• Solubility.: Chloroform (Slightly), Methanol (Slightly)

Purity/Quality:

98%min ^*data from raw suppliers

Myristic-d27 acid analytical standard ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36

MSDS Files:

SDS file from LookChem

Total 1 MSDS from other Authors

Useful:

Technology Process of TETRADECANOIC-D27 ACID

There total 2 articles about TETRADECANOIC-D27 ACID which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

n-tetradecanoic acid (544-63-8) → myristic acid-d27 (60658-41-5,327077-03-2,358730-97-9,72878-02-5)

Guidance literature:

With sodium peroxide; water-d2; platinum; at 240 ℃; for 36h;

Reference yield:

→ myristic acid-d27 (60658-41-5,327077-03-2,358730-97-9,72878-02-5)

Guidance literature:

Myristinsaeure + D2O + Pt + Na2O2.;

DOI:10.1016/0009-3084(79)90083-5

Reference yield: 85.0%

myristic acid-d27 (60658-41-5,327077-03-2,358730-97-9,72878-02-5) + 2-cyanoethyl bis-(2-O-(tert-butyldiphenylsilyl)-sn-glycer-1-yl) phosphate (1187738-15-3) → 2-cyanoethyl bis-(2-O-(tert-butyldiphenylsilyl)-3-perdeuteromyristoyl-sn-glycer-1-yl) phosphate (1187738-25-5)

Guidance literature:

myristic acid-d₂₇; With dmap; dicyclohexyl-carbodiimide; In dichloromethane; for 0.166667h;

2-cyanoethyl bis-(2-O-(tert-butyldiphenylsilyl)-sn-glycer-1-yl) phosphate; In dichloromethane; at 20 ℃; for 12h;

DOI:10.1016/j.tet.2009.06.085

upstream raw materials:

n-tetradecanoic acid

Downstream raw materials:

2-cyanoethyl bis-(2-O-(tert-butyldiphenylsilyl)-3-perdeuteromyristoyl-sn-glycer-1-yl) phosphate

Refernces