4-Nitromethylene-2,2,5,5-tetramethylimidazolidine-1-oxyl

Base Information

• Chemical Name: 4-Nitromethylene-2,2,5,5-tetramethylimidazolidine-1-oxyl
• CAS No.: 60829-54-1
• Molecular Formula: C8H14N3O3
• Molecular Weight: 0
• Mol file: 60829-54-1.mol

Synonyms:2,2,5,5-Tetramethyl-4-nitromethylen-imidazolin-1-oxyl;2,2,5,5-tetramethyl-4-nitromethyleneimidazolidin-1-oxyl;4-NITROMETHYLENE-2,2,5,5-TETRAMETHYLIMIDAZOLIDINE-1-OXYL;

Chemical Property of 4-Nitromethylene-2,2,5,5-tetramethylimidazolidine-1-oxyl

Chemical Property:

• PSA: 61.09000
• LogP: 1.65980

Purity/Quality:

99% ^*data from raw suppliers

4-NITROMETHYLENE-2,2,5,5-TETRAMETHYLIMIDAZOLIDINE-1-OXYL 95.00% ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of 4-Nitromethylene-2,2,5,5-tetramethylimidazolidine-1-oxyl

There total 3 articles about 4-Nitromethylene-2,2,5,5-tetramethylimidazolidine-1-oxyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-hydroxy-4-hydroxyiminomethyl-2,2,5,5-tetramethyl-3-imidazoline → 2,2,5,5-tetramethyl-4-nitromethyleneimidazolidine-1-oxyl (60829-54-1) + 4-hydroxyiminomethyl-2,2,5,5-tetramethyl-3-imidazolin-1-oxyl

Guidance literature:

With manganese(IV) oxide; In chloroform; for 3h; Yield given. Yields of byproduct given;

DOI:10.1007/BF00473466

Reference yield:

2,2,4,5,5-pentamethyl-2,5-dihydro-1H-imidazol-1-yloxy (39753-74-7) → 4-nitromethylene-2,2,5,5-tetramethylimidazolidin-1-oxyl (60829-54-1)

Guidance literature:

With methyl nitrate; phenyllithium; Yield given. Multistep reaction; 1) ether, r.t., 2) ether, r.t., 1 h;

Reference yield:

→ 2,2,5,5-tetramethyl-4-nitromethyleneimidazolidine-1-oxyl (60829-54-1)

Guidance literature:

1-Hydroxy-2,2,4,5,5-pentamethyl-3-imidazolin, NaNH2, fl. NH3, Amylnitril;

upstream raw materials:

2,2,4,5,5-pentamethyl-2,5-dihydro-1H-imidazol-1-yloxy

Downstream raw materials:

C₁₅H₁₆ClFN₃O₃

C₁₅H₁₇ClN₃O₃

C₁₅H₁₆Cl₂N₃O₃

4-(5-acetyl-4,5-dihydroisoxazolyl-3)-2,2,5,5-tetramethyl-3-imidazolin-1-oxyl