Bicyclo[3.1.0]hexane-1-acetic acid, -alpha--methylene- (9CI)

Base Information

Chemical Name:Bicyclo[3.1.0]hexane-1-acetic acid, -alpha--methylene- (9CI)
CAS No.:680179-44-6
Molecular Formula:C9H12O2
Molecular Weight:152.193
Hs Code.:
Mol file:680179-44-6.mol

Synonyms:Bicyclo[3.1.0]hexane-1-acetic acid, -alpha--methylene- (9CI)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Bicyclo[3.1.0]hexane-1-acetic acid, -alpha--methylene- (9CI)

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Technology Process of Bicyclo[3.1.0]hexane-1-acetic acid, -alpha--methylene- (9CI)

There total 5 articles about Bicyclo[3.1.0]hexane-1-acetic acid, -alpha--methylene- (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 540764-54-3
2-(bicyclo[3.1.0]hex-1-yl)-2-oxoacetic Acid Methyl Ester

: 680179-44-6
2-(bicyclo[3.1.0]hex-1-yl)propenoic acid

Guidance literature:: With lithium hydroxide; 2,6-di-tert-butyl-4-methyl-phenol; In water; acetone; at 20 ℃; for 24h;

Reference yield: 86.0%

: 540764-52-1
methyl 2-(bicyclo[3.1.0]hex-1-yl)propenoate

: 680179-44-6
2-(bicyclo[3.1.0]hex-1-yl)propenoic acid

Guidance literature:: With lithium hydroxide; 2,6-di-tert-butyl-4-methyl-phenol; In water; acetone; at 25 ℃; for 24h;
DOI:10.1002/adsc.200606155

Reference yield:

: 948896-29-5
8-(methoxycarbonyloxy)oct-1-en-6-yne

: 680179-44-6
2-(bicyclo[3.1.0]hex-1-yl)propenoic acid

Guidance literature:: Multi-step reaction with 2 steps

1: 94 percent / PO(OMe)3; P(2-furyl)3; P(OMe)3 / Pd(OAc)2 / methanol / 16 h / 25 °C / 750.06 Torr

2: 86 percent / LiOH; 3,5-di-tert-butyl-4-hydroxytoluene / acetone; H₂O / 24 h / 25 °C

With trimethyl phosphite; lithium hydroxide; trifuran-2-yl-phosphane; 2,6-di-tert-butyl-4-methyl-phenol; phosphorous acid trimethyl ester; palladium diacetate; In methanol; water; acetone;
DOI:10.1002/adsc.200606155