Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI)

Base Information

Chemical Name:Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI)
CAS No.:681247-97-2
Molecular Formula:C11H13NO3
Molecular Weight:207.229
Hs Code.:
Mol file:681247-97-2.mol

Synonyms:Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI)

Suppliers and Price of Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

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Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI)

Chemical Property:

Boiling Point:365.5±42.0 °C(Predicted)
PKA:1.85±0.10(Predicted)
PSA：61.55000
Density:1.154±0.06 g/cm3(Predicted)
LogP:2.28820

Purity/Quality:: 85.0-99.8% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

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Technology Process of Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI)

There total 5 articles about Benzoic acid, 6-amino-3-ethenyl-2-methoxy-, methyl ester (9CI) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 681247-97-2
methyl 6-amino-2-methoxy-3-vinylbenzoate

Guidance literature:

Reference yield: 80.0%

: 681247-48-3
methyl 6-amino-3-bromo-2-methoxybenzoate

: 4363-34-2
vinylboronic acid

: 681247-97-2
methyl 6-amino-2-methoxy-3-vinylbenzoate

Guidance literature:: With cesium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In methanol; 1,2-dimethoxyethane; at 150 ℃; for 0.0833333h; microwave irradiation;
DOI:10.1016/j.bmcl.2007.02.062

Reference yield:

: 681247-09-6
6-bromo-5-methoxy-2,4-dihydro-1H-3,1-benzoxazine-2,4-dione

: 681247-97-2
methyl 6-amino-2-methoxy-3-vinylbenzoate

Guidance literature:: Multi-step reaction with 2 steps

1: 80 percent / Heating

2: 80 percent / CsF / Pd(PPh₃)4 / 1,2-dimethoxy-ethane; methanol / 0.08 h / 150 °C / microwave irradiation

With cesium fluoride; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In methanol; 1,2-dimethoxyethane; 2: Suzuki coupling;
DOI:10.1016/j.bmcl.2007.02.062