Bis(heptafluoroisopropyl)mercury

Base Information

• Chemical Name: Bis(heptafluoroisopropyl)mercury
• CAS No.: 756-88-7
• Molecular Formula: C₆F₁₄Hg
• Molecular Weight: 538.634
• DSSTox Substance ID: DTXSID90371094
• Wikidata: Q82158337
• Mol file: 756-88-7.mol

Synonyms:Bis(heptafluoroisopropyl)mercury;756-88-7;Bis(1,1,1,2,3,3,3-heptafluoropropan-2-yl)mercury;Bis(heptafluoro-2-propyl)mercury;perfluorodiisopropylmercury;bis(perfluoropropan-2-yl)mercury;DTXSID90371094;MFCD01075251;AKOS025310354;FT-0623069;A838485;bis[1,1,1,2,3,3,3-heptakis(fluoranyl)propan-2-yl]mercury

Chemical Property of Bis(heptafluoroisopropyl)mercury

Chemical Property:

• Boiling Point: 116°C
• PSA: 0.00000
• LogP: 5.48950
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 14
• Rotatable Bond Count: 0
• Exact Mass: 539.948288
• Heavy Atom Count: 21
• Complexity: 303

Purity/Quality:

98%Min ^*data from raw suppliers

Bis(heptafluoroisopropyl)mercury ^*data from reagent suppliers

Safty Information:

• Hazard Codes: Xi,T
• Statements: 26/27/28-33
• Safety Statements: 13-28-36/37/39-45

MSDS Files:

Useful:

• Canonical SMILES: C(C(F)(F)F)(C(F)(F)F)(F)[Hg]C(C(F)(F)F)(C(F)(F)F)F

Technology Process of Bis(heptafluoroisopropyl)mercury

There total 3 articles about Bis(heptafluoroisopropyl)mercury which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

mercury(II) fluoride (7783-39-3) → bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-mercury (756-88-7)

Guidance literature:

With CF₃CFCF₃; In hydrogen fluoride; upon heating at 85°C for 24 h;;

DOI:10.1021/ja01480a044

Reference yield:

heptafluoroisopropyl silver (22407-25-6) → bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-mercury (756-88-7)

Guidance literature:

With Hg⁽²⁺⁾-halogenide; In acetonitrile; byproducts: Ag-halogenide;

Reference yield:

→ bis-(1,2,2,2-tetrafluoro-1-trifluoromethyl-ethyl)-mercury (756-88-7)

Guidance literature:

Hexafluorpropen, HgF2/HF (24h 85+-2grad);

DOI:10.1021/ja00885a016

upstream raw materials:

mercury(II) fluoride

heptafluoroisopropyl silver

Downstream raw materials:

hexafluorothioacetone

2,2,4,4-Tetrakis(trifluoromethyl)-1,3-dithietane