Cerium (IV) isopropoxide

Base Information

Chemical Name:Cerium (IV) isopropoxide
CAS No.:63007-83-0
Molecular Formula:C₃H₈O*C₁₂H₂₈CeO₄
Molecular Weight:436.568
Hs Code.:
European Community (EC) Number:679-417-0
DSSTox Substance ID:DTXSID80560733
Nikkaji Number:J1.873.554G

Synonyms:63007-83-0;CERIUM (IV) ISOPROPOXIDE;cerium(4+);propan-2-olate;Cerium(IV)isopropoxide;Cerium(IV) isopropoxide, Ce 37-45%;Cerium(4+) tetrapropan-2-olate;DTXSID80560733;AKOS025295573

Suppliers and Price of Cerium (IV) isopropoxide

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Alfa Aesar
Cerium(IV) isopropoxide, Ce 37-45%
5g
$ 423.00

Alfa Aesar
Cerium(IV) isopropoxide, Ce 37-45%
1g
$ 101.00

Total 12 raw suppliers

Chemical Property of Cerium (IV) isopropoxide

Chemical Property:

Melting Point:200°C (dec.)
Boiling Point:160-70°C/0.05mmHg
PSA：36.92000
LogP:3.50280
Sensitive.:Moisture Sensitive
Solubility.:Soluble in pyridine
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:376.10421
Heavy Atom Count:17
Complexity:10.8

Purity/Quality:

98%Min ^*data from raw suppliers

Cerium(IV) isopropoxide, Ce 37-45% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:
Statements: 36/37/38
Safety Statements: 26-36/37/39

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)[O-].CC(C)[O-].CC(C)[O-].CC(C)[O-].[Ce+4]
Uses Cerium(IV) isopropoxide, Ce 37-45% is used to catalyzes diastereoselective pinacol couplings. It forms diketonates ,which hydrolyze to CeO2 particles. CeO2 particles have the potential for ion conduction.

Technology Process of Cerium (IV) isopropoxide

There total 1 articles about Cerium (IV) isopropoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 63063-93-4
Ce(OC₃H₇-i)4*C₅H₅N

: 67-63-0,8013-70-5
isopropyl alcohol

: 63007-83-0
cerium(IV) tetrakis(isopropoxide)*i-PrOH

Guidance literature:: recrystn. 4 times from 2-propanol, drying in vac. at room temp.;

Reference yield: 31.0%

: 1,3,5,7-cycloocatetraene

: 63007-83-0
cerium(IV) tetrakis(isopropoxide)*i-PrOH

: 97-93-8
triethylaluminum

: Ce(C₈H₈)(OC₃H₇-i)Al(C₂H₅)2*0.25C₆H₅CH₃

Guidance literature:: In toluene; mole ratio of Ce(OC3H7-i)4*(i-C3H7OH) and Al(C2H5)3 = 1:3, in presence of excess C8H8, at 100 to 110°C, 24 h or more;
DOI:10.1016/S0020-1693(00)86269-6