Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)

Base Information

• Chemical Name: Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)
• CAS No.: 70625-09-1
• Molecular Formula: C17H16BF4NS2+
• Molecular Weight: 0
• Mol file: 70625-09-1.mol

Synonyms:Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)

Chemical Property of Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)

Chemical Property:

• PSA: 57.42000
• LogP: 5.84350

Purity/Quality:

99% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-)

There total 3 articles about Thiazolium, 4-methyl-3-(phenylmethyl)-2-(phenylthio)-, tetrafluoroborate(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

N-phenylthiophthalimide (14204-27-4) + 3-benzyl-4-methylthiazolium tetrafluoroborate (76756-47-3) → phthalimide (136918-14-4,85-41-6) + 3-benzyl-4-methyl-2-phenylsulfanyl-thiazolium; tetrafluoroborate (70625-09-1)

Guidance literature:

With 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; for 4h;

DOI:10.1021/jo00322a027

Reference yield:

3-Benzyl-4-methylthiazolium bromide (4356-66-5) → 3-benzyl-4-methyl-2-phenylsulfanyl-thiazolium; tetrafluoroborate (70625-09-1)

Guidance literature:

Multi-step reaction with 2 steps

1: 92 percent / AgBF₄ / ethanol

2: 86 percent / DBU / tetrahydrofuran / 4 h

With silver tetrafluoroborate; 1,8-diazabicyclo[5.4.0]undec-7-ene; In tetrahydrofuran; ethanol;

DOI:10.1021/jo00322a027

Reference yield:

N-phenylthiophthalimide (14204-27-4) + 3-benzyl-4-methylthiazolium tetrafluoroborate (76756-47-3) → 3-benzyl-4-methyl-2-phenylsulfanyl-thiazolium; tetrafluoroborate (70625-09-1)

Guidance literature:

Multistep reaction; (i) DBU, (ii) /BRN= 208408/;

DOI:10.1021/ja00504a055

upstream raw materials:

N-phenylthiophthalimide

3-benzyl-4-methylthiazolium tetrafluoroborate

3-Benzyl-4-methylthiazolium bromide