9-Mercapto-o-carborane

Base Information

Chemical Name:9-Mercapto-o-carborane
CAS No.:64493-43-2
Molecular Formula:C2H12 B10 S
Molecular Weight:176.293
Hs Code.:

Synonyms:9-Mercapto-o-carborane;o-Carboran-9-ylthiol; o-Carborane-9-thiol

Suppliers and Price of 9-Mercapto-o-carborane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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price

Total 2 raw suppliers

Chemical Property of 9-Mercapto-o-carborane

Chemical Property:

PSA：38.80000
LogP:-3.26490

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of 9-Mercapto-o-carborane

There total 4 articles about 9-Mercapto-o-carborane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 1440512-49-1
9-(triisopropylsilylmercapto)-1,2-dicarba-closo-dodecaborane

: 64493-43-2
ortho-9-mercapto-dicarba-closo-dodecaborane

Guidance literature:: With hydrogenchloride; In methanol; chloroform; water; at 40 ℃; for 48h;
DOI:10.1002/ejic.201201518

Reference yield: 80.0%

: 69289-36-7
bis(9-o-carboranyl)disulfide

: 64493-43-2
ortho-9-mercapto-dicarba-closo-dodecaborane

Guidance literature:: With zinc; In hydrogenchloride; acetic acid; to the disulfide in a mixture of CH3COOH and HCl(1:1) was carefully added excess Zn powder, mixture refluxed for 0.5 - 2 h; poured into water, extn. with ether, org. layer waashed with water, thiol extd. with 10% KOH; alkaline soln. acidified with HCl and treated with ether, solvent removed, crystn. from hexane;

Reference yield: 50.0%

: 10544-50-0
sulfur

: 72034-00-5
H₂C₂B₁₀H₉TlCl₂

: 64493-43-2
ortho-9-mercapto-dicarba-closo-dodecaborane

Guidance literature:: With lithium aluminium tetrahydride; In N,N-dimethyl-formamide; S8 added to B-compound in DMF, stirred for 6 h under reflux, poured into water, extracted (ether-benzene), org. layer dried, solvent distilled off, dissolved (THF), added dropwise to LiAlH4 in THF, stirred for 2 h at 20°C, heated for 8 h; decomposed with MeOH and water, poured into water, extracted (benzene),org. extract dried, benzene removed;
DOI:10.1007/BF00954308