(+/-)-cis- and trans-dichloro-1,2κ(2)Cl-μ-[[3-(diphenylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(diphenylphosphino-2κP)propyl]phenylphosphido-1:2κP]dipalladium

Base Information

• Chemical Name: (+/-)-cis- and trans-dichloro-1,2κ(2)Cl-μ-[[3-(diphenylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(diphenylphosphino-2κP)propyl]phenylphosphido-1:2κP]dipalladium
• CAS No.: 91550-92-4
• Molecular Formula: C₄₂H₄₂Cl₂P₄Pd₂
• Molecular Weight: 954.437
• Mol file: 91550-92-4.mol

Synonyms:

Chemical Property of (+/-)-cis- and trans-dichloro-1,2κ(2)Cl-μ-[[3-(diphenylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(diphenylphosphino-2κP)propyl]phenylphosphido-1:2κP]dipalladium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (+/-)-cis- and trans-dichloro-1,2κ(2)Cl-μ-[[3-(diphenylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(diphenylphosphino-2κP)propyl]phenylphosphido-1:2κP]dipalladium

There total 1 articles about (+/-)-cis- and trans-dichloro-1,2κ(2)Cl-μ-[[3-(diphenylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(diphenylphosphino-2κP)propyl]phenylphosphido-1:2κP]dipalladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

sodium tetrachloropalladate(II) + Diphenyl<3-(phenylphosphino)propyl>phosphin (57322-05-1) → (+/-)-cis- and trans-dichloro-1,2κ(2)Cl-μ-[[3-(diphenylphosphino-1κP)propyl]phenylphosphido-1:2κP]-μ-[[3-(diphenylphosphino-2κP)propyl]phenylphosphido-1:2κP]dipalladium (91550-92-4,91604-90-9)

Guidance literature:

In tetrahydrofuran; toluene; to suspn. of Na2PdCl4 in THF added soln. of ligand in toluene under N2; filtered, washed with Et2O, dried in vac.;

DOI:10.1021/ja00333a036

upstream raw materials:

Diphenyl<3-(phenylphosphino)propyl>phosphin