carbonylhydrido(1,10-phenanthroline)bis(methyldiphenylphosphine)ruthenium(II) perchlorate

Base Information

• Chemical Name: carbonylhydrido(1,10-phenanthroline)bis(methyldiphenylphosphine)ruthenium(II) perchlorate
• CAS No.: 107854-18-2
• Molecular Formula: C₃₉H₃₅N₂OP₂Ru*ClO₄
• Molecular Weight: 810.188
• Mol file: 107854-18-2.mol

Synonyms:

Chemical Property of carbonylhydrido(1,10-phenanthroline)bis(methyldiphenylphosphine)ruthenium(II) perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of carbonylhydrido(1,10-phenanthroline)bis(methyldiphenylphosphine)ruthenium(II) perchlorate

There total 1 articles about carbonylhydrido(1,10-phenanthroline)bis(methyldiphenylphosphine)ruthenium(II) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 58.0%

1,10-Phenanthroline (66-71-7) + (carbonyl)chloro(hydrido)tris(methyldiphenylphosphine)ruthenium(II) (107406-88-2) + sodium perchlorate → carbonylhydrido(1,10-phenanthroline)bis(methyldiphenylphosphine)ruthenium(II) perchlorate (107854-18-2)

Guidance literature:

In ethanol; dichloromethane; a soln. of the ligand in EtOH was added to a suspn. of the complex in CH2Cl2/EtOH 1/1 and the mixt. was stirred at 40°C for 1 h; concn., addn. of NaClO4;; concd., n-hexane was added, ppt. was washed with hexane and Et2O; recrystd. from n-hexane-EtOH; elem. anal.;;

DOI:10.1016/0022-328X(87)80352-2

upstream raw materials:

1,10-Phenanthroline

(carbonyl)chloro(hydrido)tris(methyldiphenylphosphine)ruthenium(II)