Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane

Base Information

Chemical Name:Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane
CAS No.:186707-07-3
Molecular Formula:C₂₂H₂₈O₄SSi
Molecular Weight:416.613
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane

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Technology Process of Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane

There total 4 articles about Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: 108-24-7
acetic anhydride

: tert-Butyl-((S)-3-oxo-3λ⁴-[1,3]oxathiolan-2-ylmethoxy)-diphenyl-silane

: 186707-07-3
Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane

Guidance literature:: With tetrabutylammonium acetate; at 120 ℃; for 6h;

Reference yield:

: 58479-61-1
tert-butylchlorodiphenylsilane

: 186707-07-3
Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane

Guidance literature:: Multi-step reaction with 2 steps

1: Im / tetrahydrofuran

2: 1.) m-chloroperbenzoic acid, 2.) (n-Bu)4NOAc / 1.) CH₂Cl₂, 2.) 120 deg C

With impramine; tetrabutylammonium acetate; 3-chloro-benzenecarboperoxoic acid; In tetrahydrofuran;
DOI:10.1021/jm00001a001

Reference yield:

: 173841-92-4
2S-t-butyldiphenylsilyloxymethyl-1,3-oxathiolane

: 186707-07-3
Trans and Cis-2S-t-butyldiphenylsilyloxymethyl-4-acetoxy-1,3-oxathiolane

Guidance literature:: Multi-step reaction with 2 steps

1: m-chloroperoxybenzoic acid / CH₂Cl₂

2: tetra-n-butylammonium acetate / 120 °C

With tetrabutylammonium acetate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1016/S0040-4039(00)76955-3