4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium

Base Information

Chemical Name:4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium
CAS No.:109532-21-0
Molecular Formula:C₄₄H₃₆ClN₈Rh₂
Molecular Weight:918.087
Hs Code.:

Synonyms:

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Chemical Property of 4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium

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Technology Process of 4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium

There total 2 articles about 4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: rhodium(II) acetate dimer

: 6631-37-4
2-(phenylamino)pyridine

: 109532-21-0
4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium

Guidance literature:: In tetrachloromethane; dichloromethane; Rh compd. and anilinopyridine were heated at 130°C for 20 h in vac., then excess of anilinopyridine was removed by sublimation, residue dissolved in CH2Cl2 contg. 10 vol % CCl4; soln. was chromd. (silicagel, EtOH/CH2Cl2 5:95), red band was collected, solvent removed; recrystn. from CH2Cl2/CH3CN;
DOI:10.1021/ic00306a012

Reference yield:

: rhodium(II) acetate dimer

: 6631-37-4
2-(phenylamino)pyridine

: 109532-21-0
Rh₂(C₅H₄NNHC₆H₅)4Cl

Guidance literature:: In neat (no solvent); the reaction of Rh2(O2CMe)4 in a melt of 2-anilinopyridine; complex was isolated; characterized by ESR;

Reference yield:

: 109532-21-0
4,0-cis-tetrakis(μ-2-anilinopyridinato)dirhodium

: 116564-36-4
Rh₂(C₅H₄NNC₆H₅)4CO

Guidance literature:: With CO; In dichloromethane; soln. of Rh complex under CO pressure of 1 atm; monitored by cyclovoltammetry;
DOI:10.1021/ic00306a012