phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)

Base Information

• Chemical Name: phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)
• CAS No.: 710341-72-3
• Molecular Formula: C₂₄H₂₄N₂PtS₂
• Molecular Weight: 599.68
• Mol file: 710341-72-3.mol

Synonyms:

Chemical Property of phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)

There total 2 articles about phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

chloro(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II) (710341-70-1) + phenylacetylene (536-74-3) → phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II) (710341-72-3)

Guidance literature:

With CuI; Et₃N; In N,N-dimethyl-formamide; PhCCH, CuI and Et3N added to DMF soln. of Pt complex; stirred at room temp. for 5 d; filtered; ppt. washed with DMF; dried under vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2004.03.003

Reference yield:

1,3-bis(1-pyrrolidinothiocarbonyl)benzene (181970-96-7) → phenylacetylide(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II) (710341-72-3)

Guidance literature:

Multi-step reaction with 2 steps

1: chloroform; acetonitrile

2: CuI; Et₃N / N,N-dimethyl-formamide

With CuI; Et₃N; In chloroform; N,N-dimethyl-formamide; acetonitrile;

DOI:10.1016/j.jorganchem.2004.03.003

upstream raw materials:

chloro(η3-S,C,S-2,6-bis(1-pyrrolidinothiocarbonyl)phenyl)platinum(II)

phenylacetylene

1,3-bis(1-pyrrolidinothiocarbonyl)benzene