didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate

Base Information

• Chemical Name: didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate
• CAS No.: 908382-54-7
• Molecular Formula: C₃₈H₆₂O₄Si₂
• Molecular Weight: 639.079
• Mol file: 908382-54-7.mol

Synonyms:

Chemical Property of didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate

There total 4 articles about didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1,2-diiodo-4,5-dimethyl-benzene (5182-67-2) → didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate (908382-54-7)

Guidance literature:

Multi-step reaction with 3 steps

1: KMnO₄; KOH / H₂O

2: H₂SO₄

3: CuI; iPr₂NH / PdCl₂(PPh₃)3

With potassium hydroxide; potassium permanganate; copper(l) iodide; sulfuric acid; diisopropylamine; bis(triphenylphosphine)palladium(II) dichloride; In water;

DOI:10.1016/j.molstruc.2006.01.049

Reference yield:

1-Decanol (112-30-1) → didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate (908382-54-7)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂SO₄

2: CuI; iPr₂NH / PdCl₂(PPh₃)3

With copper(l) iodide; sulfuric acid; diisopropylamine; bis(triphenylphosphine)palladium(II) dichloride;

DOI:10.1016/j.molstruc.2006.01.049

Reference yield:

4,5-diiodobenzene-1,2-dicarboxylic acid (82679-28-5) → didecyl 4,5-bis((trimethylsilyl)ethynyl)-1,2-benzenedicarboxylate (908382-54-7)

Guidance literature:

Multi-step reaction with 2 steps

1: H₂SO₄

2: CuI; iPr₂NH / PdCl₂(PPh₃)3

With copper(l) iodide; sulfuric acid; diisopropylamine; bis(triphenylphosphine)palladium(II) dichloride;

DOI:10.1016/j.molstruc.2006.01.049

upstream raw materials:

trimethylsilylacetylene

1-Decanol

1,2-diiodo-4,5-dimethyl-benzene

4,5-diiodobenzene-1,2-dicarboxylic acid

Downstream raw materials:

didecyl 4,5-diethynyl-1,2-benzenedicarboxylate

Refernces