LiP[PhB(μ-N-t-Bu)2]2

Base Information

• Chemical Name: LiP[PhB(μ-N-t-Bu)2]2
• CAS No.: 1026790-74-8
• Molecular Formula: C₂₈H₄₆B₂LiN₄P
• Molecular Weight: 498.237
• Mol file: 1026790-74-8.mol

Synonyms:

Chemical Property of LiP[PhB(μ-N-t-Bu)2]2

Chemical Property:

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Technology Process of LiP[PhB(μ-N-t-Bu)2]2

There total 1 articles about LiP[PhB(μ-N-t-Bu)2]2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 25.0%

bis(tert-butylamino)phenylborane dilithium salt (124652-56-8) + phosphorus trichloride (7719-12-2,52843-90-0) → LiP[PhB(μ-N-t-Bu)2]2 (1026790-74-8)

Guidance literature:

In diethyl ether; byproducts: LiCl; under Ar; soln. of Li2(PhB(N-t-Bu)2) in Et2O added to soln. of PCl3 in Et2O at -80°C; stirred at -80°C for 0.5 h and at 23°C for 16 h; filtered; filtrate concd.; crystd. from Et2O at 5°C for 5 d;

DOI:10.1021/ic702435e

upstream raw materials:

bis(tert-butylamino)phenylborane dilithium salt

phosphorus trichloride