dibenzyl{tris(trimethylsilyl)methyl}tin chloride

Base Information

Chemical Name:dibenzyl{tris(trimethylsilyl)methyl}tin chloride
CAS No.:131025-85-9
Molecular Formula:C₂₄H₄₁ClSi₃Sn
Molecular Weight:568.009
Hs Code.:

Synonyms:

Suppliers and Price of dibenzyl{tris(trimethylsilyl)methyl}tin chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dibenzyl{tris(trimethylsilyl)methyl}tin chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dibenzyl{tris(trimethylsilyl)methyl}tin chloride

There total 1 articles about dibenzyl{tris(trimethylsilyl)methyl}tin chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: tris(trimethylsilyl)methyl-lithium

: 3002-01-5
dibenzyltin(IV) dichloride

: 131025-85-9
dibenzyl{tris(trimethylsilyl)methyl}tin chloride

Guidance literature:: In tetrahydrofuran; soln. of dibenzyltin dichloride in THF is added to a soln. of Li(C(SiMe3)3) in THF under N2, reaction is refluxed gently for 15 h, mixt. is cooled, solvent is removed (vac.); remaining oil is partitioned between a chloroform-water mixt., organic layer is separated, drying (anhyd. sodium sulphate), solvent is removed, trituration (ethanol), recrystd. (chloroform-acetonitrile); elem. anal.;

Reference yield: 82.0%

: 131025-85-9
dibenzyl{tris(trimethylsilyl)methyl}tin chloride

: 131025-92-8
di(p-bromobenzyl){tris(trimethylsilyl)methyl}tin bromide

Guidance literature:: With bromine; In chloroform; soln. of bromine in chloroform is added to a soln. of Sn(CH2Ph)2(C(SiMe3)3)Cl in chloroform, stirring for 15 h at room temp. and 8 h at solvent reflux; solvent is removed (vac.), recrystd. (ethanol-chloroform); elem. anal.;

Reference yield:

: 131025-85-9
dibenzyl{tris(trimethylsilyl)methyl}tin chloride

: 131025-86-0
dibenzyl(trimethylsiloxy)(tris(trimethylsilyl)methyl)stannane

: 131025-87-1
3-(dibenzyl(tris(trimethylsilyl)methyl)stannyl)-1,1-bis(trimethylsilyl)prop-1-ene

Guidance literature:: With HBr; In diethyl ether; water; soln. of HBr in water is added dropwise at room temp. to a stirred soln. of Sn(CH2Ph)2(C(SiMe3)3)Cl in diethyl ether, stirring for 18 h, two-phase system is separated; combined ether washings are dried (anhyd. Na2SO4), removal of ether (vac.), remaining oil is recrystd. (chloroform-acetonitrile), second recrystn. yielded first Sn(CH2Ph)2(C(SiMe3)3)(OSiMe3), then Sn(CH2Ph)2(C(SiMe3)3)(CH2CHC(SiMe3)2); elem. anal.;