[TiCl₂(diphenylhydrazido^(2-))(pyridine)3]

Base Information

Chemical Name:[TiCl₂(diphenylhydrazido^(2-))(pyridine)3]
CAS No.:1085417-49-7
Molecular Formula:C₂₇H₂₅Cl₂N₅Ti
Molecular Weight:538.315
Hs Code.:

[TiCl<sub>2</sub>(diphenylhydrazido<sup>(2-)</sup>)(pyridine)3]

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Chemical Property of [TiCl₂(diphenylhydrazido^(2-))(pyridine)3]

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Technology Process of [TiCl₂(diphenylhydrazido^(2-))(pyridine)3]

There total 1 articles about [TiCl₂(diphenylhydrazido^(2-))(pyridine)3] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

: dichloro tert-butylimido trispyridine titanium(IV)

: 530-50-7
1,1-Diphenylhydrazine

: 1085417-49-7
[TiCl₂(diphenylhydrazido^(2-))(pyridine)3]

Guidance literature:: In benzene; byproducts: (CH3)3CNH2; (inert atm.); addn. of benzene soln. of hydrazine deriv. to stirred benzene soln. of titanium compd. for 15 min, stirring for 14 h; filtration, washing with pentane, drying in vac., elem. anal.;
DOI:10.1021/om8007597

Reference yield: 99.0%

: 1085417-49-7
[TiCl₂(diphenylhydrazido^(2-))(pyridine)3]

: 870457-30-0
[TiCl₂(diphenylhydrazido^(2-))(pyridine)2]2

Guidance literature:: In neat (no solvent); byproducts: C5H5N; (inert atm.); keeping in vac. at 4E-2 mbar for 14 h; washing with pentane, NMR;
DOI:10.1021/om8007597

Reference yield: 73.0%

: 1085417-49-7
[TiCl₂(diphenylhydrazido^(2-))(pyridine)3]

: Li₂((2-NC₅H₄)C(Me)(CH₂NSiMe₃)2)

: 1085417-57-7
[Ti(C₅H₄NC(Me)(CH₂NSiMe₃)2)(diphenylhydrazido^(2-))(pyridine)]

Guidance literature:: In toluene; (inert atm.); addn. of lithium compd. in toluene to stirred suspn. of titanium compd. in toluene at -78°C for 15 min, warming to room temp., stirring for 14 h; evapn., extn. (diethyl ether), filtration, evapn., washing with pentane,drying in vac., elem. anal.;
DOI:10.1021/om8007597