(1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum

Base Information

• Chemical Name: (1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum
• CAS No.: 155864-13-4
• Molecular Formula: C₄₂H₃₀MoN₄O₄Si
• Molecular Weight: 778.75
• Mol file: 155864-13-4.mol

Synonyms:

Chemical Property of (1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum

There total 2 articles about (1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.7%

tetraphenyloxalamidine-tetracarbonylmolybdenum (155864-06-5) + diphenylsilyl dichloride (80-10-4) → (1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum (155864-13-4)

Guidance literature:

With sodium bis(trimethylsilyl)amide; In tetrahydrofuran; byproducts: NaCl; addn. of the amide to a soln. of the Mo-compd. in THF at room temp., dropwise addn. of the silane in THF and stirring for 2 h; removal of pptd. NaCl by filtn. and partial evapn. of solvent, crystn. by addn. of Et2O, filtering off and washing;

Reference yield:

N(1),N(2),N(3),N(4)-tetraphenyloxalamidine (1516-85-4,109314-79-6) → (1,3-diphenyl-2-diphenylsila-4,5-bis(phenylimino)imidazolidine)tetracarbonylmolybdenum (155864-13-4)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene

2: sodium bis(trimethylsilyl)amide / tetrahydrofuran

With sodium bis(trimethylsilyl)amide; In tetrahydrofuran; toluene;

upstream raw materials:

tetraphenyloxalamidine-tetracarbonylmolybdenum

diphenylsilyl dichloride

N⁽¹⁾,N⁽²⁾,N⁽³⁾,N⁽⁴⁾-tetraphenyloxalamidine