C₂₁H₁₉NiS₃Se^(1-)*C₂₄H₂₀P⁽¹⁺⁾

Base Information

• Chemical Name: C₂₁H₁₉NiS₃Se^(1-)*C₂₄H₂₀P⁽¹⁺⁾
• CAS No.: 1572948-49-2
• Molecular Formula: C₂₁H₁₉NiS₃Se*C₂₄H₂₀P
• Molecular Weight: 844.626
• Mol file: 1572948-49-2.mol

Synonyms:

Chemical Property of C₂₁H₁₉NiS₃Se^(1-)*C₂₄H₂₀P⁽¹⁺⁾

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₂₁H₁₉NiS₃Se^(1-)*C₂₄H₂₀P⁽¹⁺⁾

There total 4 articles about C₂₁H₁₉NiS₃Se^(1-)*C₂₄H₂₀P⁽¹⁺⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 67.0%

selenium (7782-49-2) + C12H8S3(2-)*Ni(2+) + tetraphenylphosphonium bromide (2751-90-8) + 2-mesitylmagnesium bromide (2633-66-1) → C21H19NiS3Se(1-)*C24H20P(1+) (1572948-49-2)

Guidance literature:

selenium; 2-mesitylmagnesium bromide; In diethyl ether; Schlenk technique; Glovebox;

C₁₂H₈S₃^(2-)*Ni⁽²⁺⁾; In tetrahydrofuran; diethyl ether; for 1h; Schlenk technique; Glovebox;

tetraphenylphosphonium bromide; In tetrahydrofuran; methanol; diethyl ether; for 0.333333h; Schlenk technique; Glovebox;

DOI:10.1039/c3dt52967c

Reference yield:

C21H19NiS4(1-)*C24H20P(1+) (1572948-50-5) → C21H19NiS3Se(1-)*C24H20P(1+) (1572948-49-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: oxygen / dichloromethane / 120 h

2.1: diethyl ether / Schlenk technique; Glovebox

2.2: 1 h / Schlenk technique; Glovebox

2.3: 0.33 h / Schlenk technique; Glovebox

With oxygen; In diethyl ether; dichloromethane;

DOI:10.1039/c3dt52967c

Reference yield:

C21H19NiS3Se(1-)*C16H36N(1+) (1572948-46-9) → C21H19NiS3Se(1-)*C24H20P(1+) (1572948-49-2)

Guidance literature:

Multi-step reaction with 2 steps

1.1: dichloromethane / 0.5 h / Schlenk technique; Glovebox

2.1: diethyl ether / Schlenk technique; Glovebox

2.2: 1 h / Schlenk technique; Glovebox

2.3: 0.33 h / Schlenk technique; Glovebox

In diethyl ether; dichloromethane;

DOI:10.1039/c3dt52967c

upstream raw materials:

selenium

tetraphenylphosphonium bromide

2-mesitylmagnesium bromide

C₂₁H₁₉NiS₃Se^(1-)*C₁₆H₃₆N⁽¹⁺⁾

Downstream raw materials:

dimesityl diselenide

C₂₁H₁₉NiS₄^(1-)*C₁₆H₃₆N⁽¹⁺⁾

C₂₁H₁₉NiS₄^(1-)*C₂₄H₂₀P⁽¹⁺⁾

bis(2,4,6-trimethylphenyl)disulfide