(β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine

Base Information

• Chemical Name: (β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine
• CAS No.: 125708-47-6
• Molecular Formula: C₂₀H₃₁PSiSn
• Molecular Weight: 449.235
• Mol file: 125708-47-6.mol

Synonyms:

Chemical Property of (β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine

There total 1 articles about (β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

diphenyl-(1-trimethylsilanyl-vinyl)-phosphane (125708-42-1) + trimethylstannane (1631-73-8) → (β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine (125708-47-6) + (trimethylstannyl)diphenylphosphine (1213-51-0)

Guidance literature:

Irradiation (UV/VIS); Equimolar mixture of Me3SnH and vinyldiphenylphosphine compound in a quartz Schlenk tube is irradiated under Ar for 12 h (high-pressure mercury lamp).; distn. under reduced pressure;

DOI:10.1016/0022-328X(89)85311-2

Reference yield: 61.0%

(β-trimethylstannyl)CH2CH(SiMe3)diphenylphosphine (125708-47-6) → (β-trimethylstannyl)CH2CH(SiMe3)(diphenylphosphine oxide) (125708-45-4)

Guidance literature:

With potassium permanganate; In acetone; byproducts: manganese dioxide; The stannyl-substituted phosphine is dissolved in acetone and treated with a saturated soln. of KMnO4 in acetone (under Ar).; MnO2 is filtered off, solvent removal, crystn. of residue on standing, recrystn. (CH2Cl2/n-hexane 1/9), elem. anal.;

DOI:10.1016/0022-328X(89)85311-2

upstream raw materials:

diphenyl-(1-trimethylsilanyl-vinyl)-phosphane

trimethylstannane

Downstream raw materials:

(β-trimethylstannyl)CH2CH(SiMe3)(diphenylphosphine oxide)