(Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)PF₆

Base Information

• Chemical Name: (Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)PF₆
• CAS No.: 137966-89-3
• Molecular Formula: C₃₇H₂₉Mo₂O₄*F₆P
• Molecular Weight: 874.479

Synonyms:

Chemical Property of (Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)PF₆

Chemical Property:

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Useful:

Technology Process of (Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)PF₆

There total 1 articles about (Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)⁽¹⁺⁾*PF₆^(1-)=(Mo(C₅H₅)(CO)2)2(HCCCHCH₂C(C₆H₅)3)PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

(Mo(C5H5)(CO)2)2(HCCCHCH2) (137966-85-9) + tritylium hexafluorophosphate (437-17-2) → (Mo(C5H5)(CO)2)2(HCCCHCH2C(C6H5)3)(1+)*PF6(1-)=(Mo(C5H5)(CO)2)2(HCCCHCH2C(C6H5)3)PF6 (137966-89-3)

Guidance literature:

In dichloromethane; transferring soln. of Mo-complex to soln. of (C6H5)3CPF6 at -20°C; stirring for 4h at room temp. (N2); evapn. (vac.); chromy. of residue (Florisil, CH2Cl2/THF, orange band); elem. anal.;

Reference yield: 40.0%

(Mo(C5H5)(CO)2)2(HCCCHCH2C(C6H5)3)(1+)*PF6(1-)=(Mo(C5H5)(CO)2)2(HCCCHCH2C(C6H5)3)PF6 (137966-89-3) → (Mo(C5H5)(CO)2)2(HCCCHCHC(C6H5)3) (137966-95-1)

Guidance literature:

With 1,8-diazabicyclo{5.4.0}undec-7-ene or NaH; In dichloromethane; dissolving ionic Mo-complex in CH2Cl2 at -20°C; dropwise addn. of DBU; stirring for 1h, orange soln. turned red (N2); evapn. (vac.); chromy. (silica gel, hexane/CH2Cl2 3:1); elem. anal.;

Reference yield: 20.0%

sodium tetrahydroborate (16940-66-2) + (Mo(C5H5)(CO)2)2(HCCCHCH2C(C6H5)3)(1+)*PF6(1-)=(Mo(C5H5)(CO)2)2(HCCCHCH2C(C6H5)3)PF6 (137966-89-3) → (Mo(C5H5)(CO)2)2(HCCHCHCH2C(C6H5)3) (137966-94-0) + (Mo(C5H5)(CO)2)2(HCCCH2CH2C(C6H5)3) (137966-93-9)

Guidance literature:

In tetrahydrofuran; dissolving ionic Mo-complex in THF in the presence of a large excess of NaBH4; color of soln. changed from orange to red; stirring at room temp. for 4h (N2); filtration; evapn. (vac.); chromy. (silica gel, hexane/CH2Cl2 2:1) yielded alkyl-alkyne-Mo-complex; alkenyl-Mo-complex from CH2Cl2 - eluent, removing solvent; elem. anal.;

upstream raw materials:

(Mo(C₅H₅)(CO)2)2(HCCCHCH₂)

tritylium hexafluorophosphate

Downstream raw materials:

(Mo(C₅H₅)(CO)2)2(HCCHCHCH₂C(C₆H₅)3)

(Mo(C₅H₅)(CO)2)2(HCCCH₂CH₂C(C₆H₅)3)

(Mo(C₅H₅)(CO)2)2(HCCCHCHC(C₆H₅)3)

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