[CH(C(methyl)N(2,6-dimethylphenyl))₂Li]

Base Information

• Chemical Name: [CH(C(methyl)N(2,6-dimethylphenyl))₂Li]
• CAS No.: 482323-03-5
• Molecular Formula: C₂₁H₂₅N₂*Li
• Molecular Weight: 312.384
• Mol file: 482323-03-5.mol

Synonyms:

Chemical Property of [CH(C(methyl)N(2,6-dimethylphenyl))₂Li]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [CH(C(methyl)N(2,6-dimethylphenyl))₂Li]

There total 2 articles about [CH(C(methyl)N(2,6-dimethylphenyl))₂Li] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

2-(2,6-dimethylphenyl)amine-4-(2,6-dimethylphenyl)imine-2-pentene (267431-79-8) → [CH(C(methyl)N(2,6-dimethylphenyl))2Li] (482323-03-5,604806-75-9)

Guidance literature:

With n-butyllithium; In hexane; at -90 - 20 ℃; for 1h; Inert atmosphere; Schlenk technique;

DOI:10.1002/zaac.201800100

Reference yield:

acetylacetone (1522-20-9,26567-75-9,72036-58-9) + 2,6-dimethylaniline (87-62-7) → [CH(C(methyl)N(2,6-dimethylphenyl))2Li] (482323-03-5,604806-75-9)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / Acidic conditions; Inert atmosphere

2: n-butyllithium / pentane / Inert atmosphere

With n-butyllithium; In toluene; pentane;

DOI:10.1021/om2006479

Reference yield: 95.0%

chloromethyl(1,5-cyclooctadiene)palladium(II) + [CH(C(methyl)N(2,6-dimethylphenyl))2Li] (482323-03-5,604806-75-9) + acetonitrile (75-05-8,26809-02-9) → (CH(C(CH3)NC6H3(CH3)2)2)PdMe(acetonitrile) (1178538-65-2) + (CH(C(CH3)NC6H3(CH3)2)2)Pd(η3-6-methylcyclooctenyl) + (CH(C(CH3)NC6H3(CH3)2)2)Pd(η3-6-phenylcyclooctenyl) (1178538-64-1)

Guidance literature:

In benzene; byproducts: LiCl; (N2); dissolving palladium compd., CH3CN and ketiminate deriv. in benzene, stirring overnight at room temp.; filtration, evapn., diffusion of petroleum ether at low temp., NMR ans MS;

DOI:10.1021/om900171d

upstream raw materials:

2-(2,6-dimethylphenyl)amine-4-(2,6-dimethylphenyl)imine-2-pentene

acetylacetone

2,6-dimethylaniline

Downstream raw materials:

([{N-(C₆H₃Me₂-2,6)C(Me)}₂CH]^?Cu⁺)

Yb(C₅H₅)2(C₆H₃(CH₃)2NCCH₃CHCCH₃NC₆H₃(CH₃)2)

YbCl₂(C₄H₈O)2(C₆H₃(CH₃)2NCCH₃CHCCH₃NC₆H₃(CH₃)2)

[NdCl₂(tetrahydrofuran)2((2,6-C₆H₃Me₂)NHC(Me)CHC(Me)N(2,6-C₆H₃Me₂))]