PdCl₂(CH(P(C₆H₅)3)COOCH₃)2

Base Information

• Chemical Name: PdCl₂(CH(P(C₆H₅)3)COOCH₃)2
• CAS No.: 58300-15-5
• Molecular Formula: C₄₂H₃₈Cl₂O₄P₂Pd
• Molecular Weight: 846.035
• Mol file: 58300-15-5.mol

Synonyms:

Chemical Property of PdCl₂(CH(P(C₆H₅)3)COOCH₃)2

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of PdCl₂(CH(P(C₆H₅)3)COOCH₃)2

There total 3 articles about PdCl₂(CH(P(C₆H₅)3)COOCH₃)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

bis(benzonitrile)palladium(II) dichloride (15617-18-2,39958-10-6,14220-64-5) + methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) → PdCl2(CH(P(C6H5)3)COOCH3)2 (125875-42-5,58300-15-5)

Guidance literature:

In acetone; addn. of the ylide to a soln. of Pd-compd. in acetone, stirring for 24 h at room temp.; filtration, washing with diethyl ether; elem. anal.;

DOI:10.1016/0022-328X(89)87150-5

Reference yield: 82.0%

methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) + palladium dichloride → PdCl2(CH(P(C6H5)3)COOCH3)2 (125875-42-5,58300-15-5)

Guidance literature:

In acetonitrile; addn. of a satd. soln. of PdCl2 in CH3CN to the ylide, stirring of suspension for 15 min at room temp.; filtration, washing with diethyl ether;

DOI:10.1016/0022-328X(89)87150-5

Reference yield: 77.0%

methyl (triphenylphosphoranylidene)acetate (21204-67-1,2605-67-6) + palladium dichloride → PdCl2(CH(P(C6H5)3)COOCH3)2 (125875-42-5,58300-15-5) + {Pd(CH(P(2-C6H4)Ph2)(COOMe))(μ-Cl)}2

Guidance literature:

In acetonitrile; byproducts: ((C6H5)3PCH2COOCH3)Cl; dissoln. of PdCl2 under reflux with CH3CN, addn. of the ylide, 3 min reflux, rapid cooing of suspension to room temp.; filtration, washing with diethyl ether, evapn. of mother liquor to dryness, extn. with acetone, filtration of extract yields a 2. crop of main product, sepn. of 2. product in mixture with (Ph3PCH2COOCH3)Cl by concn. of the filtrate and addn. of ether;

DOI:10.1016/0022-328X(89)87150-5

upstream raw materials:

bis(benzonitrile)palladium(II) dichloride

methyl (triphenylphosphoranylidene)acetate