((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium

Base Information

Chemical Name:((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium
CAS No.:732946-01-9
Molecular Formula:C₂₈H₃₀O₃P
Molecular Weight:445.518
Hs Code.:

Synonyms:

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Chemical Property of ((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium

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Technology Process of ((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium

There total 7 articles about ((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 53293-00-8
hex-5-ynoic acid

: 732946-01-9
((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium

Guidance literature:: Multi-step reaction with 7 steps

1: 1.) C₂H₅MgBr; 2.) CuBr / 1.) THF, 0 deg C; 2.) 0 deg C for 15 min, reflux for 8 h.

3: 89 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 4 h / 23 °C

4: 99 percent / H₂ / Lindlar / tetrahydrofuran / 0.75 h / 23 °C

5: 99 percent / potassium bromide / tetrahydrofuran; aq. acetic acid / 10 h / 0 °C

6: 92 percent / Jones reagens / 1.5 h / 23 °C

7: CHCl₃ / 3 h / Heating

With Jones Reagens; ethylmagnesium bromide; hydrogen; 3-chloro-benzenecarboperoxoic acid; potassium bromide; copper(I) bromide; Lindlar's catalyst; In tetrahydrofuran; dichloromethane; chloroform; acetic acid;
DOI:10.1016/S0040-4039(01)81539-2

Reference yield:

: 96202-79-8
non-5-yn-8-enoic acid

: 732946-01-9
((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium

Guidance literature:: Multi-step reaction with 6 steps

2: 89 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 4 h / 23 °C

3: 99 percent / H₂ / Lindlar / tetrahydrofuran / 0.75 h / 23 °C

4: 99 percent / potassium bromide / tetrahydrofuran; aq. acetic acid / 10 h / 0 °C

5: 92 percent / Jones reagens / 1.5 h / 23 °C

6: CHCl₃ / 3 h / Heating

With Jones Reagens; hydrogen; 3-chloro-benzenecarboperoxoic acid; potassium bromide; Lindlar's catalyst; In tetrahydrofuran; dichloromethane; chloroform; acetic acid;
DOI:10.1016/S0040-4039(01)81539-2

Reference yield:

: 96202-80-1
methyl non-5-yn-8-enoate

: 732946-01-9
((Z)-8-Methoxycarbonyl-2-oxo-oct-4-enyl)-triphenyl-phosphonium

Guidance literature:: Multi-step reaction with 5 steps

1: 89 percent / m-chloroperbenzoic acid / CH₂Cl₂ / 4 h / 23 °C

2: 99 percent / H₂ / Lindlar / tetrahydrofuran / 0.75 h / 23 °C

3: 99 percent / potassium bromide / tetrahydrofuran; aq. acetic acid / 10 h / 0 °C

4: 92 percent / Jones reagens / 1.5 h / 23 °C

5: CHCl₃ / 3 h / Heating

With Jones Reagens; hydrogen; 3-chloro-benzenecarboperoxoic acid; potassium bromide; Lindlar's catalyst; In tetrahydrofuran; dichloromethane; chloroform; acetic acid;
DOI:10.1016/S0040-4039(01)81539-2