tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium

Base Information

• Chemical Name: tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium
• CAS No.: 134043-73-5
• Molecular Formula: C₆₂H₃₈Cl₈N₂O₈P₂Ru₂
• Molecular Weight: 1486.7
• Mol file: 134043-73-5.mol

Synonyms:

Chemical Property of tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium

There total 1 articles about tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

4,4'-bipyridine (553-26-4) + ((ruthenium(carbonyl)2(PPh3)(μ-o-O2C6Cl4))2) → tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium (134043-73-5)

Guidance literature:

In dichloromethane; react. under N2; addn. of 4,4'bipy to stirred soln. of Ru-complex, pptn.; under N2; addn. of hexane after 15 min, soln. concentrated in vac., ppt. washed with hexane, dried in vac.; elem. anal.;

DOI:10.1016/0022-328X(91)86483-7

Reference yield:

tetracarbonyl-bis(tetrachloro-o-catecholato)-bis(triphenylphosphine)(μ-4,4'-bipyridyl)diruthenium (134043-73-5) + {(Ru(CO)2(P(C6H5)3)(O2C6Cl4))2(C5H4N)2}(2+) → {(Ru(CO)2(P(C6H5)3)(O2C6Cl4))2(C5H4N)2}(1+)

Guidance literature:

react. under N2; not detd. by IR, ESR, UV or cyclovoltammetry;

DOI:10.1016/0022-328X(91)86483-7

upstream raw materials:

4,4'-bipyridine