alpha-D-Glucopyranoside, phenyl 1-seleno-, tetraacetate

Base Information

Chemical Name:alpha-D-Glucopyranoside, phenyl 1-seleno-, tetraacetate
CAS No.:23661-29-2
Molecular Formula:C₂₀H₂₄O₉Se
Molecular Weight:487.365
Hs Code.:
DSSTox Substance ID:DTXSID201223314
Nikkaji Number:J545.455G

Synonyms:DTXSID201223314;alpha-D-Glucopyranoside, phenyl 1-seleno-, tetraacetate;1-(Phenylseleno)-1-deoxy-alpha-D-glucopyranose 2,3,4,6-tetraacetate;23661-29-2

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of alpha-D-Glucopyranoside, phenyl 1-seleno-, tetraacetate

Chemical Property:

Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:9
Rotatable Bond Count:11
Exact Mass:488.05855
Heavy Atom Count:30
Complexity:632

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC(=O)OCC1C(C(C(C(O1)[Se]C2=CC=CC=C2)OC(=O)C)OC(=O)C)OC(=O)C
Isomeric SMILES:CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@H](O1)[Se]C2=CC=CC=C2)OC(=O)C)OC(=O)C)OC(=O)C

Technology Process of alpha-D-Glucopyranoside, phenyl 1-seleno-, tetraacetate

There total 15 articles about alpha-D-Glucopyranoside, phenyl 1-seleno-, tetraacetate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 645-96-5
Benzeneselenol

: 604-69-3
β-D-glucose pentaacetate

: 23661-29-2,23661-30-5
phenyl 2,3,4,6-tetra-O-acetyl-1-seleno-β-D-glucopyranoside

Guidance literature:: With indium(III) bromide; In dichloromethane; at 20 ℃; for 2h; stereoselective reaction;
DOI:10.1055/s-0036-1588507

Reference yield: 92.0%

: 1666-13-3
diphenyl diselenide

: 572-09-8
2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide

: 23661-29-2,23661-30-5
phenyl 2,3,4,6-tetra-O-acetyl-1-seleno-β-D-glucopyranoside

Guidance literature:: diphenyl diselenide; With zinc(II) chloride; zinc; In acetonitrile; at 70 ℃; for 0.75h;

2,3,4,6-tetra-O-acetyl-α-D-glucopyranosyl bromide; In acetonitrile; at 70 ℃; for 0.75h;
DOI:10.1016/j.tetlet.2005.11.074

Reference yield: 90.0%

: 869107-17-5
4'-methylbenzoyl 2,3,4,6-tetra-O-acetyl-β-D-selenoglucopyranoside

: 591-50-4
iodobenzene

: 23661-29-2,23661-30-5
phenyl 2,3,4,6-tetra-O-acetyl-1-seleno-β-D-glucopyranoside

Guidance literature:: With piperazine; palladium [2'-(amino-κN)[1,1'-biphenyl]-2-yl-κC][[5-(diphenylphosphino)-9,9-dimethyl-9H-xanthen-4-yl]diphenylphosphine-κP](methanesulfonato-κO); caesium carbonate; In tetrahydrofuran; at 20 ℃; for 2h; Inert atmosphere; Sealed tube;
DOI:10.1021/acs.orglett.0c02352