3-allyl-1,2-diphenyl-4,5-dihydrophosphole sulfide

Base Information

• Chemical Name: 3-allyl-1,2-diphenyl-4,5-dihydrophosphole sulfide
• CAS No.: 1259008-81-5
• Molecular Formula: C₁₉H₁₉PS
• Molecular Weight: 310.4
• Mol file: 1259008-81-5.mol

Synonyms:

Chemical Property of 3-allyl-1,2-diphenyl-4,5-dihydrophosphole sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3-allyl-1,2-diphenyl-4,5-dihydrophosphole sulfide

There total 1 articles about 3-allyl-1,2-diphenyl-4,5-dihydrophosphole sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

ethylmagnesium bromide (925-90-6) + Dichlorophenylphosphine (644-97-3) + 1-phenyl-4-penten-1-yne (4289-20-7) → 3-allyl-1,2-diphenyl-4,5-dihydrophosphole sulfide (1259008-81-5) + 2-allyl-1,3-diphenyl-4,5-dihydrophosphole sulfide (1259008-89-3)

Guidance literature:

ethylmagnesium bromide; With zirconocene dichloride; In tetrahydrofuran; at -78 ℃; Inert atmosphere;

1-phenyl-4-penten-1-yne; In tetrahydrofuran; at 0 ℃; for 1h; Inert atmosphere;

Dichlorophenylphosphine; With sulfur; In tetrahydrofuran; at 20 ℃; Inert atmosphere;

DOI:10.1016/j.tetlet.2010.09.061

upstream raw materials:

ethylmagnesium bromide

Dichlorophenylphosphine

1-phenyl-4-penten-1-yne

Refernces