C₁₃H₃S₆⁽¹⁺⁾*C₂₄BF₂₀^(1-)

Base Information

• Chemical Name: C₁₃H₃S₆⁽¹⁺⁾*C₂₄BF₂₀^(1-)
• CAS No.: 1425265-66-2
• Molecular Formula: C₁₃H₃S₆*C₂₄BF₂₀
• Molecular Weight: 1030.61
• Mol file: 1425265-66-2.mol

Synonyms:

Chemical Property of C₁₃H₃S₆⁽¹⁺⁾*C₂₄BF₂₀^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₃H₃S₆⁽¹⁺⁾*C₂₄BF₂₀^(1-)

There total 6 articles about C₁₃H₃S₆⁽¹⁺⁾*C₂₄BF₂₀^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

3,4,6,7-tetrakis(methanesulfonyloxy)-9-hydroxyphenalen-1-one (1425265-59-3) → C13H3S6(1+)*C24BF20(1-) (1425265-66-2)

Guidance literature:

Multi-step reaction with 3 steps

1.1: potassium thioacetate / N,N-dimethyl-formamide / 72 h / 20 °C / Inert atmosphere; Schlenk technique

2.1: Lawessons reagent / chlorobenzene / 36 h / 135 °C / Inert atmosphere; Schlenk technique

2.2: 135 °C / Inert atmosphere; Schlenk technique

3.1: dichloromethane / 2 h / 20 °C / Inert atmosphere; Schlenk technique

With Lawessons reagent; potassium thioacetate; In dichloromethane; N,N-dimethyl-formamide; chlorobenzene;

DOI:10.1021/ol400452f

Reference yield:

1,3,6,8-tetramethoxynaphthalene (17276-03-8) → C13H3S6(1+)*C24BF20(1-) (1425265-66-2)

Guidance literature:

Multi-step reaction with 7 steps

1.1: dichloromethane / 0.5 h / 0 °C / Inert atmosphere; Schlenk technique

1.2: 18 h / 0 - 20 °C / Inert atmosphere; Schlenk technique

2.1: hydrogenchloride; water / 20 - 85 °C / Inert atmosphere; Schlenk technique

3.1: pyridine hydrochloride / 4 h / 180 °C / Inert atmosphere; Schlenk technique

4.1: triethylamine / dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Schlenk technique

4.2: 20 °C / Inert atmosphere

5.1: potassium thioacetate / N,N-dimethyl-formamide / 72 h / 20 °C / Inert atmosphere; Schlenk technique

6.1: Lawessons reagent / chlorobenzene / 36 h / 135 °C / Inert atmosphere; Schlenk technique

6.2: 135 °C / Inert atmosphere; Schlenk technique

7.1: dichloromethane / 2 h / 20 °C / Inert atmosphere; Schlenk technique

With Lawessons reagent; hydrogenchloride; water; pyridine hydrochloride; triethylamine; potassium thioacetate; In dichloromethane; N,N-dimethyl-formamide; chlorobenzene;

DOI:10.1021/ol400452f

Reference yield:

3-oxo-3-(2,4,5,7-tetramethoxynaphthalen-1-yl)propionic acid ethyl ester (1335551-15-9) → C13H3S6(1+)*C24BF20(1-) (1425265-66-2)

Guidance literature:

Multi-step reaction with 6 steps

1.1: hydrogenchloride; water / 20 - 85 °C / Inert atmosphere; Schlenk technique

2.1: pyridine hydrochloride / 4 h / 180 °C / Inert atmosphere; Schlenk technique

3.1: triethylamine / dichloromethane / 0.5 h / 20 °C / Inert atmosphere; Schlenk technique

3.2: 20 °C / Inert atmosphere

4.1: potassium thioacetate / N,N-dimethyl-formamide / 72 h / 20 °C / Inert atmosphere; Schlenk technique

5.1: Lawessons reagent / chlorobenzene / 36 h / 135 °C / Inert atmosphere; Schlenk technique

5.2: 135 °C / Inert atmosphere; Schlenk technique

6.1: dichloromethane / 2 h / 20 °C / Inert atmosphere; Schlenk technique

With Lawessons reagent; hydrogenchloride; water; pyridine hydrochloride; triethylamine; potassium thioacetate; In dichloromethane; N,N-dimethyl-formamide; chlorobenzene;

DOI:10.1021/ol400452f

upstream raw materials:

1,3,6,8-tetramethoxynaphthalene

1,2,4,5,7,8-hexathiophenalenylium triflate

3-oxo-3-(2,4,5,7-tetramethoxynaphthalen-1-yl)propionic acid ethyl ester

3,4,6,7,9-pentahydroxyphenalen-1-one