1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Base Information

Chemical Name:1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene
CAS No.:878277-53-3
Molecular Formula:C₂₆H₂₄FeO
Molecular Weight:408.323
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

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Technology Process of 1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

There total 2 articles about 1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

: propionylferrocene

: 1137-42-4
4-Hydroxybenzophenone

: 878277-53-3,198059-86-8,198059-85-7
1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Guidance literature:: With titanium tetrachloride; zinc; In tetrahydrofuran; under Ar; TiCl4 was added dropwise to a suspn. of Zn in THF at -10°C, the mixt. was heated at reflux for 1.5 h, allowed to cool to room temp., ketone and complex were added dropwise, the mixt. was heated for 2h, cooled to room temp.; hydrolyzed with 10% K2CO3, extd. with ether, solvent was removed, chromy. (silica gel, Et2O/pentane); elem. anal.;
DOI:10.1016/S0022-328X(01)00953-6

Reference yield:

: 198059-83-5,198059-84-6
1-(4-methoxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

: 878277-53-3,198059-86-8,198059-85-7
1-(4-hydroxyphenyl)-1-(phenyl)-2-ferrocenyl-but-1-ene

Guidance literature:: With BBr₃; In dichloromethane; Ar-atmosphere; addn. of equimolar amt. of BBr3 to Fe-complex soln. at -78°C, stirring for 30 min and warming; pouring into ice water, stirring for 10 min, addn. of NaCl, extn. into CH2Cl2, washing of org. phase (aq. Na2S2O3, H2O), drying (MgSO4), filtration, solvent removal, crystn.;
DOI:10.1016/S0022-328X(97)00086-7