(3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one

Base Information

Chemical Name:(3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one
CAS No.:55076-60-3
Molecular Formula:C25H24O5
Molecular Weight:404.463
Hs Code.:
Mol file:55076-60-3.mol

Synonyms:2H-Cyclopenta[b]furan-2-one,5-(benzoyloxy)hexahydro-4-(3-oxo-5-phenyl-1-pentenyl)-, [3aR-[3aa,4a(E),5b,6aa]]-;2H-Cyclopenta[b]furan-2-one,5-(benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-, (3aR,4R,5R,6aS)-(9CI);PGX 6;

Suppliers and Price of (3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Matrix Scientific
(3AR,4R,5R,6aS)-2-Oxo-4-((E)-3-oxo-5-phenylpent-1-en-1-yl)hexahydro-2H-cyclopenta[b]furan-5-yl benzoate 95+%
250mg
$ 742.00

Matrix Scientific
(3AR,4R,5R,6aS)-2-Oxo-4-((E)-3-oxo-5-phenylpent-1-en-1-yl)hexahydro-2H-cyclopenta[b]furan-5-yl benzoate 95+%
1g
$ 1647.00

Crysdot
(3aR,4R,5R,6aS)-2-Oxo-4-((E)-3-oxo-5-phenylpent-1-en-1-yl)hexahydro-2H-cyclopenta[b]furan-5-ylbenzoate 95+%
1g
$ 772.00

Chemenu
(3AR,4R,5R,6aS)-2-Oxo-4-((E)-3-oxo-5-phenylpent-1-en-1-yl)hexahydro-2H-cyclopenta[b]furan-5-ylbenzoate 95%
1g
$ 729.00

Biosynth Carbosynth
(3AR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one
25 mg
$ 405.00

Biosynth Carbosynth
(3AR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one
10 mg
$ 203.00

Biosynth Carbosynth
(3AR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one
5 mg
$ 117.00

Biosynth Carbosynth
(3AR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one
2 mg
$ 59.00

Biosynth Carbosynth
(3AR,4R,5R,6aS)-5-(benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one
50 mg
$ 704.00

American Custom Chemicals Corporation
(3AR,4R,5R,6AS)-2-OXO-4-((E)-3-OXO-5-PHENYLPENT-1-EN-1-YL)HEXAHYDRO-2H-CYCLOPENTA[B]FURAN-5-YL BENZOATE 95.00%
5MG
$ 501.14

Total 46 raw suppliers

Chemical Property of (3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one

Chemical Property:

Vapor Pressure:1.12E-14mmHg at 25°C
Melting Point:117-118 °C
Refractive Index:1.604
Boiling Point:606.9 °C at 760 mmHg
Flash Point:263 °C
PSA：69.67000
Density:1.25 g/cm³
LogP:3.92170
Storage Temp.:2-8°C

Purity/Quality:

97% ^*data from raw suppliers

(3AR,4R,5R,6aS)-2-Oxo-4-((E)-3-oxo-5-phenylpent-1-en-1-yl)hexahydro-2H-cyclopenta[b]furan-5-yl benzoate 95+% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one

There total 9 articles about (3aR,4R,5R,6aS)-5-(Benzoyloxy)hexahydro-4-[(1E)-3-oxo-5-phenyl-1-pentenyl]-2H-cyclopenta[b]furan-2-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.43%

: 1174193-89-5
4-phenyl-1-(1-phenyl-1H-tetrazole-5-sulfonyl)butan-2-one

: 39746-01-5
(1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one

: 55076-60-3
(3aR,4R,5R,6aS)-2-oxo-4-((1E)-3-oxo-5-phenylpent-1-en-1-yl)-hexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Guidance literature:: With potassium tert-butylate; In dichloromethane; tert-butyl alcohol; at -60 - -55 ℃; Solvent; Inert atmosphere;

Reference yield: 84.7%

: 41162-19-0
dimethyl(2-oxo-4-phenylbutyl)phosphonate

: 39746-01-5
(1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one

: 55076-60-3
(3aR,4R,5R,6aS)-2-oxo-4-((1E)-3-oxo-5-phenylpent-1-en-1-yl)-hexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Guidance literature:: dimethyl(2-oxo-4-phenylbutyl)phosphonate; With N-ethyl-N,N-diisopropylamine; lithium chloride; In acetonitrile; at -15 ℃;

(1S,5R,6R,7R)-6-formyl-7-benzoyloxy-2-oxabicyclo[3.3.0]octan-3-one; In acetonitrile; at -15 ℃;

Reference yield:

: 31984-10-8
1-bromo-4-phenylbutan-2-one

: 55076-60-3
(3aR,4R,5R,6aS)-2-oxo-4-((1E)-3-oxo-5-phenylpent-1-en-1-yl)-hexahydro-2H-cyclopenta[b]furan-5-yl benzoate

Guidance literature:: Multi-step reaction with 2 steps

1: acetonitrile / 1 h / 80 °C

2: lithium chloride; triethylamine / tetrahydrofuran / 2 h / -4 - 20 °C

With triethylamine; lithium chloride; In tetrahydrofuran; acetonitrile; 2: |Horner-Wadsworth-Emmons Olefination;