rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol

Base Information

Chemical Name:rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol
CAS No.:83173-76-6
Molecular Formula:C₁₂H₁₆O
Molecular Weight:176.258
Hs Code.:
DSSTox Substance ID:DTXSID601171254
Nikkaji Number:J502.573G

Synonyms:DTXSID601171254;83173-76-6;rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol

Suppliers and Price of rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol

Chemical Property:

XLogP3:2.9
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:3
Exact Mass:176.120115130
Heavy Atom Count:13
Complexity:157

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC1=CC=C(C=C1)C(C(C)C=C)O
Isomeric SMILES:CC1=CC=C(C=C1)[C@@H]([C@H](C)C=C)O

Technology Process of rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol

There total 30 articles about rel-(alphaR)-4-Methyl-alpha-[(1R)-1-methyl-2-propen-1-yl]benzenemethanol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: (2R,3S)-3-Methyl-2-(2,4,6-trimethyl-phenyl)-pent-4-en-2-ol

: 104-87-0
4-methyl-benzaldehyde

: 83173-76-6,136106-31-5
(syn)-2-methyl-1-(p-methylphenyl)-3-buten-1-ol

Guidance literature:: (2R,3S)-3-Methyl-2-(2,4,6-trimethyl-phenyl)-pent-4-en-2-ol; With methyl magnesium iodide; In diethyl ether; at -20 ℃; for 1h;

4-methyl-benzaldehyde; With gallium(III) trichloride; In diethyl ether; hexane; at -20 ℃; for 30h;
DOI:10.1021/ol0515199

Reference yield:

: 4784-77-4,29576-14-5,39616-19-8
(E/Z)-crotyl bromide

: 104-87-0
4-methyl-benzaldehyde

: 83173-76-6,136106-31-5
(anti)-2-methyl-1-(p-methylphenyl)-3-buten-1-ol

: 83173-76-6,136106-31-5
(syn)-2-methyl-1-(p-methylphenyl)-3-buten-1-ol

Guidance literature:: With (3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid; potassium iodide; lithium chloride; In tetrahydrofuran; Yield given; Yields of byproduct given; Heating;
DOI:10.1080/00397919908086104

Reference yield:

: 4784-77-4,29576-14-5,39616-19-8
(E/Z)-crotyl bromide

: 104-87-0
4-methyl-benzaldehyde

: 83173-76-6,136106-31-5
(anti)-2-methyl-1-(p-methylphenyl)-3-buten-1-ol

: 83173-76-6,136106-31-5
(syn)-2-methyl-1-(p-methylphenyl)-3-buten-1-ol

Guidance literature:: With (3S,3aS,4S,4aS,6S,8aR,8bR,11S)-6,11-dihydroxy-3-methyl-12-methylene-2-oxo-4a,6-ethano-3,8b-prop-1-enoperhydroindeno[1,2-b]furan-4-carboxylic acid; potassium iodide; lithium chloride; In tetrahydrofuran; Yield given; Yields of byproduct given; Heating;
DOI:10.1080/00397919908086104