(R)-2-naphthyl methyl sulfoxide

Base Information

• Chemical Name: (R)-2-naphthyl methyl sulfoxide
• CAS No.: 101541-53-1
• Molecular Formula: C₁₁H₁₀OS
• Molecular Weight: 190.266
• Mol file: 101541-53-1.mol

Synonyms:

Chemical Property of (R)-2-naphthyl methyl sulfoxide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of (R)-2-naphthyl methyl sulfoxide

There total 13 articles about (R)-2-naphthyl methyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-methylthionaphthalene (7433-79-6) → (R)-2-naphthyl methyl sulfoxide (35330-76-8,101541-53-1,114129-50-9,18690-03-4)

Guidance literature:

With C₈₈H₉₀N₂O₆P₂; dihydrogen peroxide; magnesium sulfate; In cyclohexane; water; at 20 ℃; for 2h; optical yield given as %ee; enantioselective reaction;

DOI:10.1021/ja3035637

Reference yield: 98.0%

→ (R)-2-naphthyl methyl sulfoxide (35330-76-8,101541-53-1,114129-50-9,18690-03-4)

Guidance literature:

With C₈₈H₈₉NO₆P₂; dihydrogen peroxide; magnesium sulfate; In cyclohexane; at 20 ℃; for 2h;

Reference yield: 73.0%

2-methylthionaphthalene (7433-79-6) → 2-(methylsulfonyl)naphthalene (35330-75-7) + (R)-2-naphthyl methyl sulfoxide (35330-76-8,101541-53-1,114129-50-9,18690-03-4)

Guidance literature:

2-methylthionaphthalene; With bis(acetylacetonate)oxovanadium; (R)-2-((1-hydroxy-3,3-dimethylbutan-2-ylimino)methyl)-4,6-diiodophenol; In chloroform; at 20 ℃; for 0.5h;

With dihydrogen peroxide; In chloroform; at 0 ℃;

DOI:10.1002/anie.200503046

upstream raw materials:

2-methylthionaphthalene

methylmagnesium bromide

2-methanesulfinylnaphthalene

2-(2-naphthylsulfanyl)ethyl phenyl sulfone

Downstream raw materials:

2-methanesulfinylnaphthalene