14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

Base Information

Chemical Name:14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione
CAS No.:207982-22-7
Molecular Formula:C₄₄H₅₁N₃O₁₅S
Molecular Weight:893.966
Hs Code.:

14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

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Chemical Property of 14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

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Technology Process of 14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

There total 7 articles about 14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

: 207982-20-5
14-Benzyloxycarbonyl-1-chloro-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-4,5-dihydrotripyrrin-10(17H)-one

: 207982-22-7
14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

Guidance literature:: With hydrogen sulfide; silver(I) acetate; In dichloromethane; for 0.166667h; Ambient temperature;
DOI:10.1039/a708134k

Reference yield:

: 50622-64-5
benzyl 3-(2-methoxycarbonylethyl)-4-methoxycarbonylmethyl-5-methylpyrrole-2-carboxylate

: 207982-22-7
14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

Guidance literature:: Multi-step reaction with 7 steps

1: t-BuOCl / tetrahydrofuran / 3 h / Ambient temperature

2: tetrahydrofuran / 0.25 h

3: 1.) POCl₃ / 1.) 60 deg C, 30 min, 2.) 1,2-dichloroethene, 70 deg C, 4 h

4: t-BuOCl / tetrahydrofuran; diethyl ether / 0.33 h / 0 °C

5: AcONa / 1 h / 60 °C

6: 1.) SnCl₄, 2.) glacial AcOH / 1.) C₆H₆, r.t., 45 min, 2.) r.t., 1 h

7: 60 percent / H₂S, AgOAc / CH₂Cl₂ / 0.17 h / Ambient temperature

With tert-butylhypochlorite; hydrogen sulfide; silver(I) acetate; sodium acetate; tin(IV) chloride; acetic acid; trichlorophosphate; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1039/a708134k

Reference yield:

: 74855-24-6
5-Chlorocarbonyl-3-(2-methoxycarbonyl-ethyl)-4-methoxycarbonylmethyl-1H-pyrrole-2-carboxylic acid benzyl ester

: 207982-22-7
14-Benzyloxycarbonyl-2,8,13-tris(2-methoxycarbonylethyl)-3,7,12-tris(methoxycarbonylmethyl)-4-methyl-10-oxo-4,5,10,17-tetrahydrotripyrrin-1(15H)-thione

Guidance literature:: Multi-step reaction with 6 steps

1: tetrahydrofuran / 0.25 h

2: 1.) POCl₃ / 1.) 60 deg C, 30 min, 2.) 1,2-dichloroethene, 70 deg C, 4 h

3: t-BuOCl / tetrahydrofuran; diethyl ether / 0.33 h / 0 °C

4: AcONa / 1 h / 60 °C

5: 1.) SnCl₄, 2.) glacial AcOH / 1.) C₆H₆, r.t., 45 min, 2.) r.t., 1 h

6: 60 percent / H₂S, AgOAc / CH₂Cl₂ / 0.17 h / Ambient temperature

With tert-butylhypochlorite; hydrogen sulfide; silver(I) acetate; sodium acetate; tin(IV) chloride; acetic acid; trichlorophosphate; In tetrahydrofuran; diethyl ether; dichloromethane;
DOI:10.1039/a708134k