bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical^(1-))nickel(II)

Base Information

• Chemical Name: bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical^(1-))nickel(II)
• CAS No.: 78802-18-3
• Molecular Formula: C₃₈H₄₄N₄Ni
• Molecular Weight: 615.484

Synonyms:

Chemical Property of bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical^(1-))nickel(II)

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Technology Process of bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical^(1-))nickel(II)

There total 2 articles about bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical^(1-))nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

[Ni(cyclododeca-1,5,9-triene)] (39330-67-1) + 2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene (78788-25-7) → bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical(1-))nickel(II) (78802-18-3)

Guidance literature:

In diethyl ether; under Ar; soln. of Ni complex in Et2O added to soln. of ligand in Et2O; stirred at room temp. overnight; solvent removed by evapn. under reduced pressure; ppt. washed with MeCN;dried in vac.; elem. anal.;

DOI:10.1039/b709390j

Reference yield:

nickel(II) bromide dimethoxyethane (28923-39-9) + 2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene (78788-25-7) → bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical(1-))nickel(II) (78802-18-3)

Guidance literature:

With Na; In tetrahydrofuran; under Ar; 3 d; evapn. of the volatiles, the residue is extd. (benzene), an oil is obtained;

Reference yield: 87.0%

ferrocenium hexafluorophosphate + bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene radical(1-))nickel(II) (78802-18-3) → bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene)nickel(I) hexafluorophosphate (958229-53-3)

Guidance literature:

In dichloromethane; Fe complex added with stirring to soln. of Ni complex in CH2Cl2 at 20°C for 1.5 h; filtered; filtrate concd. by evapn. under reduced pressure; n-hexane added; stirred for 1 h; filtered; ppt. washed with n-hexane; dried in vac.;elem. anal.;

DOI:10.1039/b709390j

upstream raw materials:

[Ni(cyclododeca-1,5,9-triene)]

2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene

nickel(II) bromide dimethoxyethane

Downstream raw materials:

bis(2-methyl-1,4-bis(2,6-dimethylphenyl)-1,4-diaza-1,3-butadiene)nickel(I) hexafluorophosphate

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