cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate

Base Information

Chemical Name:cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate
CAS No.:68812-17-9
Molecular Formula:BF₄*C₂₄H₂₁MnO₄PS
Molecular Weight:578.211
Hs Code.:

Synonyms:

Suppliers and Price of cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate

There total 4 articles about cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 75-18-3
dimethylsulfide

: 68812-00-0
cis-aquatetracarbonyl(triphenylphosphine)manganese tetrafluoroborate

: 68812-17-9
cis-(dimethyl sulphide)tetracarbonyl(triphenylphosphine)manganese tetrafluoroborate

Guidance literature:: In not given; N2-atmosphere; stirring (room temp., 5 min); pptn. on hexane addn., solvent removal (vac.), recrystn. (CH2Cl2/hexane); elem. anal.;
DOI:10.1039/DT9780001009

Reference yield: 86.0%

: 67047-38-5
[bis(triphenylphospine)nitrogen⁽¹⁺⁾][Mn(CO)4(PPh₃)]

: 5799-67-7
dimethyl(methylthio)sulfonium tetrafluoroborate

: 68812-17-9
trans-{Mn(CO)4(SMe₂)(PPh₃)}BF₄

: bis(triphenylphosphoranylidene)ammonium tetrafluoroborate

Guidance literature:: In dichloromethane; dry N2atmosphere; -78 °C, stirring, warming to romm temp.; evapn. (N2 flow overnight); crystn. (CH2Cl2/ethyl acetate); (PPN)BF4 isolation;redn. of vol. of mother liquor; pptn. of Mn-complex on layering with ethyl acetate;
DOI:10.1016/0022-328X(89)85429-4

Reference yield: 43.0%

: 2Mn*8CO*2(P(C₆H₅)3) = Mn₂(CO)8(P(C₆H₅)3)2

: 5799-67-7
dimethyl(methylthio)sulfonium tetrafluoroborate

: 68812-17-9
trans-{Mn(CO)4(SMe₂)(PPh₃)}BF₄

Guidance literature:: In dichloromethane; 1 equivalent (Me2SSMe)BF4, under dry nitrogen; soln. redn.; pptn. of product on layering with ethyl acetate; fractional cristn. (CH2Cl2/ethyl acetate), elem. anal.;
DOI:10.1016/0022-328X(89)85429-4