C₁₄H₁₂O₃

Base Information

• Chemical Name: C₁₄H₁₂O₃
• CAS No.: 16241-31-9
• Molecular Formula: C₁₄H₁₂O₃
• Molecular Weight: 228.247
• Mol file: 16241-31-9.mol

Synonyms:

Chemical Property of C₁₄H₁₂O₃

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₁₄H₁₂O₃

There total 5 articles about C₁₄H₁₂O₃ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 62.0%

C14H11BrO3 → C14H12O3 (1411674-13-9,16241-31-9)

Guidance literature:

C₁₄H₁₁BrO₃; With 1,3-dimethyl-3,4,5,6-tetrahydro-2(1H)-pyrimidinone; In tetrahydrofuran; for 0.333333h; Inert atmosphere;

With samarium diiodide; at 20 ℃; for 0.00833333h; Inert atmosphere;

With sodium hydroxide; In water; at 20 ℃; for 6h; Inert atmosphere;

DOI:10.1039/c2ob26553b

Reference yield:

2-Amino-4-<4-methoxy-phenyl>-tropon (16241-28-4) → 4-(4-Methoxy-phenyl)-tropolon (16241-31-9)

Guidance literature:

With potassium hydroxide; In ethanol;

DOI:10.1246/bcsj.40.1462

Reference yield:

7-(4-methoxyphenyl)cyclohepta-1,3,5-triene (29304-87-8) → 4-(4-Methoxy-phenyl)-tropolon (16241-31-9)

Guidance literature:

Multi-step reaction with 3 steps

1: (i) (heating), (ii) SeO₂, H₂O, dioxane

2: N₂H₄*H₂O / ethanol

3: aq. KOH / ethanol

With potassium hydroxide; hydrazine hydrate; In ethanol;

DOI:10.1246/bcsj.40.1462

upstream raw materials:

2-Amino-4-<4-methoxy-phenyl>-tropon

7-(4-methoxyphenyl)cyclohepta-1,3,5-triene

4-<4-Methoxy-phenyl>-tropon