(+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

Base Information

Chemical Name:(+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene
CAS No.:120708-39-6
Molecular Formula:C₃₀H₂₂BrF₃O₃
Molecular Weight:567.402
Hs Code.:

(+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydro<e>pyrene

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Chemical Property of (+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

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Technology Process of (+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

There total 2 articles about (+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 41.0%

: 20445-33-4,39637-99-5
(R)-methoxytrifluoromethylphenylacetyl chloride

: 88767-14-0
(+/-)-trans-10-Bromo-9-hydroxy-9,10,11,12-tetrahydrobenzopyrene

: 120624-78-4,120708-39-6
(+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

: 120624-78-4
(-)-(9R,10R)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

Guidance literature:: With pyridine; dmap; for 20h; Ambient temperature;
DOI:10.1039/P19880003013

Reference yield:

: 66788-01-0
9,10-Dihydrobenzopyrene

: 120624-78-4,120708-39-6
(+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / N-bromosuccinimide / tetrahydrofuran; H₂O / 0 °C

2: 37 percent / 4-dimethylaminopyridine, pyridine, / 20 h / Ambient temperature

With pyridine; dmap; N-Bromosuccinimide; In tetrahydrofuran; water;
DOI:10.1039/P19880003013

Reference yield:

: 120624-78-4,120708-39-6
(+)-(9S,10S)-10-bromo-9-<(2S)-3,3,3-trifluoro-2-methoxy-2-phenylpropionyloxy>-9,10,11,12-tetrahydropyrene

: 88824-55-9,82132-21-6
(-)-(9S,10R)-9,10-Epoxy-9,10,11,12-tetrahydrobenzopyrene

Guidance literature:: Multi-step reaction with 2 steps

1: 83 percent / DIBAL / diethyl ether; hexane / 1) 0 deg C, 30 min, 2) RT, overnight

2: 92 percent / Amberlite resin (IRA-900) / tetrahydrofuran / 2 h / Ambient temperature

With Amberlite resin (IRA-900); diisobutylaluminium hydride; In tetrahydrofuran; diethyl ether; hexane;
DOI:10.1039/P19880003013