[Mo₂(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)]

Base Information

• Chemical Name: [Mo₂(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)]
• CAS No.: 944556-72-3
• Molecular Formula: C₅₁H₄₉Mo₂N₇O₈
• Molecular Weight: 1079.87
• Mol file: 944556-72-3.mol

Synonyms:

Chemical Property of [Mo₂(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of [Mo₂(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)]

There total 2 articles about [Mo₂(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

pyridine-4-carboxylic acid (55-22-1) + Mo2(N,N′-di(p-anisyl)formamidinate)3(O2CCH3) (581775-94-2) → [Mo2(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)] (944556-72-3)

Guidance literature:

With NaOCH₃; In tetrahydrofuran; methanol; byproducts: sodium acetate; under N2; to soln. of complex in THF was added NaOCH3 in MeOH, stirring for ca. 2 h, ppt. was filtered off, to filtrate excess of isonicotinic acid was added, stirring at room temp. for 0.5 h; solvent was removed under vac., residue was washed with EtOH, dried in vac., solid was dissolved in CH2Cl2, soln. was layered with hexanes, crystals formed after one day; elem. anal.;

DOI:10.1039/b617932k

Reference yield:

pyridine-4-carboxylic acid (55-22-1) + [Mo2(N,N′-di(p-anisyl)formamidinate)3(acetate)] → [Mo2(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)] (944556-72-3)

Guidance literature:

[Mo₂(N,N′-di(p-anisyl)formamidinate)₃(acetate)]; With sodium methylate; In tetrahydrofuran; methanol; for 2h;

pyridine-4-carboxylic acid; at 20 ℃; for 3h;

DOI:10.1021/acs.inorgchem.6b02525

Reference yield: 31.0%

{Rh2(acetate)4(acetonitrile)2} (80419-75-6) + [Mo2(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)] (944556-72-3) → [Mo2(N,N'-di(p-anisyl)formamidinate)3(isonicotinate)]2[Rh2(CO2CH3)4]

Guidance literature:

In acetonitrile; under N2; mixt. was stirred at room temp. for 4 h; solvent was removed under reduced pressure, residue was washed with EtOH, ppt. was dissolved in CH2Cl2 and soln. was layered with hexanes, crystals were formed after one day; elem. anal.;

DOI:10.1039/b617932k

upstream raw materials:

pyridine-4-carboxylic acid

Mo₂(N,N′-di(p-anisyl)formamidinate)₃(O₂CCH₃)