(C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅PF₆

Base Information

• Chemical Name: (C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅PF₆
• CAS No.: 396693-16-6
• Molecular Formula: C₄₉H₄₂NP₂Ru*F₆P
• Molecular Weight: 952.861
• Mol file: 396693-16-6.mol

Synonyms:

Chemical Property of (C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅PF₆

There total 1 articles about (C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅⁽¹⁺⁾*PF₆^(1-)=(C₅H₅)(P(C₆H₅)3)2RuNCCH₂C₆H₅PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

ammonium hexafluorophosphate + Ru(phenylacetylene)(PPh3)2Cp + trimethylsilylazide (4648-54-8) → (C5H5)(P(C6H5)3)2RuNCCH2C6H5(1+)*PF6(1-)=(C5H5)(P(C6H5)3)2RuNCCH2C6H5PF6 (396693-16-6)

Guidance literature:

In tetrahydrofuran; Ru-complex was dissolved in THF, Me3SiN3 was added, stirred for 8 h under N2, NH4PF6 was added, stirred at 0°C for 3 h; filtered, concd., hexane was added, filtered, washed with hexane;

DOI:10.1039/b104635g

upstream raw materials:

trimethylsilylazide