cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

Base Information

Chemical Name:cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin
CAS No.:123284-05-9
Molecular Formula:C₂₂H₂₆O₂
Molecular Weight:322.447
Hs Code.:

Synonyms:

Suppliers and Price of cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

There total 4 articles about cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.0%

: 123186-09-4
(2RS,7SR)-(Z)-2,7-diphenethyl-2,3,6,7-tetrahydrooxepine

: 123186-10-7
trans-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

: 123284-05-9
cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

Guidance literature:: With 3-chloro-benzenecarboperoxoic acid; In dichloromethane; for 6h; Ambient temperature;
DOI:10.1021/jo00285a016

Reference yield:

: 71221-09-5
1-methoxy-3-phenyl-1-propene

: 123284-05-9
cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

Guidance literature:: Multi-step reaction with 3 steps

1: 44 percent / pyridinium p-toluenesulfonate (PPTS) / CH₂Cl₂ / 20.5 h / Ambient temperature

2: 84 percent / EtAlCl₂ / heptane / 1.) -78 deg C, 20 min, 2.) 0 deg C, 1.5 h

3: 14 percent / m-chloroperoxybenzoic acid (m-CPBA) / CH₂Cl₂ / 6 h / Ambient temperature

With ethylaluminum dichloride; pyridinium p-toluenesulfonate; 3-chloro-benzenecarboperoxoic acid; In n-heptane; dichloromethane;
DOI:10.1021/jo00285a016

Reference yield:

: 123186-26-5
1-phenyl-6-(trimethylsilyl)-6-hepten-3-ol

: 123284-05-9
cis-2,7-bis(2-phenylethyl)-4,5-epoxy-2,3,4,5,6,7-hexahydrooxepin

Guidance literature:: Multi-step reaction with 3 steps

1: 44 percent / pyridinium p-toluenesulfonate (PPTS) / CH₂Cl₂ / 20.5 h / Ambient temperature

2: 84 percent / EtAlCl₂ / heptane / 1.) -78 deg C, 20 min, 2.) 0 deg C, 1.5 h

3: 14 percent / m-chloroperoxybenzoic acid (m-CPBA) / CH₂Cl₂ / 6 h / Ambient temperature

With ethylaluminum dichloride; pyridinium p-toluenesulfonate; 3-chloro-benzenecarboperoxoic acid; In n-heptane; dichloromethane;
DOI:10.1021/jo00285a016