Technology Process of C23H30N2Si
There total 4 articles about C23H30N2Si which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
C17H15BrN2;
With
sodium hydride;
In
tetrahydrofuran;
at 20 ℃;
Glovebox;
Inert atmosphere;
With
n-butyllithium;
In
tetrahydrofuran; hexane;
at -78 ℃;
for 3h;
Schlenk technique;
Inert atmosphere;
chlorodiisopropylsilane;
With
hydrogenchloride;
In
tetrahydrofuran; hexane; water;
at 20 ℃;
for 19h;
DOI:10.1021/ja311682c
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: N-Bromosuccinimide / acetonitrile / 3.5 h / 0 - 20 °C
2.1: 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; palladium diacetate; sodium tert-pentoxide / toluene / 48 h / 115 °C / Glovebox; Inert atmosphere
3.1: sodium hydride / tetrahydrofuran / 20 °C / Glovebox; Inert atmosphere
3.2: 3 h / -78 °C / Schlenk technique; Inert atmosphere
3.3: 19 h / 20 °C
With
N-Bromosuccinimide; palladium diacetate; sodium tert-pentoxide; sodium hydride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl;
In
tetrahydrofuran; toluene; acetonitrile;
DOI:10.1021/ja311682c
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: sodium iodide; sulfuric acid / 1.05 h / 0 - 140 °C / Schlenk technique
2.1: 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; palladium diacetate; sodium tert-pentoxide / toluene / 48 h / 115 °C / Glovebox; Inert atmosphere
3.1: sodium hydride / tetrahydrofuran / 20 °C / Glovebox; Inert atmosphere
3.2: 3 h / -78 °C / Schlenk technique; Inert atmosphere
3.3: 19 h / 20 °C
With
sulfuric acid; palladium diacetate; sodium tert-pentoxide; sodium hydride; 2,2'-bis-(diphenylphosphino)-1,1'-binaphthyl; sodium iodide;
In
tetrahydrofuran; toluene;
DOI:10.1021/ja311682c
