Phenmedipham-ethyl

Base Information

Chemical Name:Phenmedipham-ethyl
CAS No.:13684-44-1
Molecular Formula:C17H18N2O4
Molecular Weight:314.339
Hs Code.:2924299090
European Community (EC) Number:802-885-6
UNII:Z56KWX34F9
DSSTox Substance ID:DTXSID2075009
Nikkaji Number:J22.314J
Wikidata:Q27295013
Mol file:13684-44-1.mol

Synonyms:Phenmedipham-ethyl;13684-44-1;Phenmedipham-ethyl [ISO];(3-Methylphenyl)carbamic acid 3-[(ethoxycarbonyl)amino]phenyl ester;Ethyl (3-((m-tolylcarbamoyl)oxy)phenyl)carbamate;Z56KWX34F9;[3-(ethoxycarbonylamino)phenyl] N-(3-methylphenyl)carbamate;Carbamic acid, (3-methylphenyl)-, 3-((ethoxycarbonyl)amino)phenyl ester;Phenmedipham ethyl;UNII-Z56KWX34F9;(3-methylphenyl)carbamic acid 3-((ethoxycarbonyl)amino)phenyl ester;3-((ETHOXYCARBONYL)AMINO)PHENYL N-(3-METHYLPHENYL)CARBAMATE;3-[(ETHOXYCARBONYL)AMINO]PHENYL N-(3-METHYLPHENYL)CARBAMATE;ethyl 3-(3-methylcarbaniloyloxy)carbanilate;SCHEMBL134424;3-Ethoxycarbonylaminophenyl N-3-methylphenylcarbamate;DTXSID2075009;AMY7522;BCP33325;MFCD13194954;BS-53170;CS-0151528;Phenmedipham-ethyl 100 microg/mL in Acetone;Ethyl(3-((m-tolylcarbamoyl)oxy)phenyl)carbamate;Phenmedipham-ethyl, PESTANAL(R), analytical standard;Q27295013;ETHYL N-(3-(N-(3-METHYLPHENYL)CARBAMOYLOXY)PHENYL)CARBAMATE;CARBANILIC ACID, M-METHYL-, ESTER WITH ETHYL M-HYDROXYCARBANILATE;ETHYL N-(3-(N'-(3'-METHYLPHENYL)CARBAMOYLOXY)PHENYL)CARBAMATE;CARBAMIC ACID, N-(3-METHYLPHENYL)-, 3-((ETHOXYCARBONYL)AMINO)PHENYL ESTER;CARBANILIC ACID, M-HYDROXY-, ETHYL ESTER, M-METHYLCARBANILATE (ESTER);SN-38574;Ethyl N-[3-[N'-(3-methylphenyl)carbamoyloxy]phenyl]carbamate

Suppliers and Price of Phenmedipham-ethyl

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
Phenmedipham-ethyl PESTANAL
25mg
$ 165.00

Crysdot
Ethyl(3-((m-tolylcarbamoyl)oxy)phenyl)carbamate 97%
100mg
$ 316.00

American Custom Chemicals Corporation
PHENMEDIPHAM-ETHYL 95.00%
5MG
$ 502.74

Ambeed
Ethyl(3-((m-tolylcarbamoyl)oxy)phenyl)carbamate 98%
1g
$ 481.00

Ambeed
Ethyl(3-((m-tolylcarbamoyl)oxy)phenyl)carbamate 98%
250mg
$ 204.00

Ambeed
Ethyl(3-((m-tolylcarbamoyl)oxy)phenyl)carbamate 98%
100mg
$ 138.00

Total 21 raw suppliers

Chemical Property of Phenmedipham-ethyl

Chemical Property:

Vapor Pressure:8.75E-07mmHg at 25°C
Melting Point:140-144 °C
Refractive Index:1.628
Boiling Point:405.5 °C at 760 mmHg
PKA:12.96±0.70(Predicted)
Flash Point:199 °C
PSA：76.66000
Density:1.274 g/cm³
LogP:4.32030
Storage Temp.:-20°C Freezer, Under inert atmosphere
Solubility.:Chloroform (Slightly), Methanol (Slightly)
XLogP3:4
Hydrogen Bond Donor Count:2
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:6
Exact Mass:314.12665706
Heavy Atom Count:23
Complexity:402

Purity/Quality:

99% ^*data from raw suppliers

Phenmedipham-ethyl PESTANAL ^*data from reagent suppliers

Safty Information:

Pictogram(s): N
Hazard Codes:N
Statements: 50/53
Safety Statements: 60-61

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CCOC(=O)NC1=CC(=CC=C1)OC(=O)NC2=CC=CC(=C2)C
Uses Phenmedipham-ethyl is used as an agrochemical bioregulator. Phenmedipham-ethyl is an impurity of Phenmedipham (P314600); a carbanilate selective herbicide used post-emergence in beet crops after the emergence of most broad-leaved weeds and before they develop.

Technology Process of Phenmedipham-ethyl

There total 3 articles about Phenmedipham-ethyl which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 621-29-4
3-tolyl isocyanate

: 7159-96-8
ethyl N-(3-hydroxyphenyl)carbamate

: 13684-44-1
3-Ethoxycarbonylaminophenyl-N-(m-methyl-phenyl)-carbamat

Guidance literature:: With triethylamine; In benzene; for 0.5h; Reflux;
DOI:10.1016/j.bioorg.2018.03.012

Reference yield:

: 591-27-5
m-Hydroxyaniline

: 13684-44-1
3-Ethoxycarbonylaminophenyl-N-(m-methyl-phenyl)-carbamat

Guidance literature:: Multi-step reaction with 2 steps

1: tetrahydrofuran / 2 h / 20 °C

2: triethylamine / benzene / 0.5 h / Reflux

With triethylamine; In tetrahydrofuran; benzene;
DOI:10.1016/j.bioorg.2018.03.012