N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO¹)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester

Base Information

• Chemical Name: N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO¹)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester
• CAS No.: 65422-77-7
• Molecular Formula: C₄₀H₄₈N₂O₁₃S
• Molecular Weight: 796.893
• Mol file: 65422-77-7.mol

Synonyms:

Chemical Property of N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO¹)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO¹)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester

There total 1 articles about N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO¹)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ C40H48N2O13S (65422-77-7)

Guidance literature:

Aus entspr. 9-Hydroxy-Deriv. u. Tosylchlorid-Pyridin;

Reference yield:

N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO1)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester (65422-77-7) → ((3aR)-8t-benzoyloxy-2,2,5c,9-tetramethyl-10-oxo-(3ar,6at,7ac,8ac,11ac,12at,13atO1)-decahydro-[1,3]dioxolo[4''',5''':3'',4'']pyrano[2'',3'':5',6'][1,4]dioxino[2',3':4,5]benzo[1,2-d]oxazol-12t-yl)-methyl-carbamic acid benzyl ester (67421-61-8,68927-36-6)

Guidance literature:

Multi-step reaction with 2 steps

1: BaO / dimethylformamide

2: dimethylformamide

With barium(II) oxide; In N,N-dimethyl-formamide;

DOI:10.7164/antibiotics.31.985

Reference yield:

N,N'-dimethyl-N,N'-[(3aR)-10t-hydroxy-2,2,5c-trimethyl-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,11at,12atO1)-octahydro-benzo[b][1,3]dioxolo[4',5':3,4]pyrano[2,3-e][1,4]dioxine-9t,11t-diyl]-bis-carbamic acid dibenzyl ester (65422-77-7) → methyl-[(3aR)-2,2,5c,9-tetramethyl-10-oxo-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,8ac,11ac,12at,13atO1)-decahydro-[1,3]dioxolo[4''',5''':3'',4'']pyrano[2'',3'':5',6'][1,4]dioxino[2',3':4,5]benzo[1,2-d]oxazol-12t-yl]-carbamic acid benzyl ester (68846-22-0)

Guidance literature:

With barium(II) oxide; In N,N-dimethyl-formamide;

DOI:10.7164/antibiotics.31.985

Downstream raw materials:

methyl-[(3aR)-2,2,5c,9-tetramethyl-10-oxo-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,8ac,11ac,12at,13atO¹)-decahydro-[1,3]dioxolo[4''',5''':3'',4'']pyrano[2'',3'':5',6'][1,4]dioxino[2',3':4,5]benzo[1,2-d]oxazol-12t-yl]-carbamic acid benzyl ester

methyl-[(3aR)-2,2,5c,12-tetramethyl-11-oxo-8c-(toluene-4-sulfonyloxy)-(3ar,6at,7ac,9ac,12ac,12bt,13atO¹)-decahydro-[1,3]dioxolo[3''',4''':3'',4'']pyrano[3'',2'':5',6'][1,4]dioxino[2',3':5,6]benzo[1,2-d]oxazol-9t-yl]-carbamic acid benzyl ester

((3aR)-8t-benzoyloxy-2,2,5c,9-tetramethyl-10-oxo-(3ar,6at,7ac,8ac,11ac,12at,13atO¹)-decahydro-[1,3]dioxolo[4''',5''':3'',4'']pyrano[2'',3'':5',6'][1,4]dioxino[2',3':4,5]benzo[1,2-d]oxazol-12t-yl)-methyl-carbamic acid benzyl ester