(S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX

Base Information

Chemical Name:(S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX
CAS No.:913829-88-6
Molecular Formula:C39H34 N O P
Molecular Weight:563.679
Hs Code.:
Mol file:913829-88-6.mol

Synonyms:(S,S)-7-[4-(benzyl)oxazol-2-yl]-7'-diphenylphosphinyl-1,1'-spirobiindane;(Sa,S)-7-[4-(Benzyl)oxazol-2-yl]-7 inverted exclamation marka-diphenylphosphinyl-1,1 inverted exclamation marka-spirobiinane;

Suppliers and Price of (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Strem Chemicals
(S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,2,3,3-tetrahydro-1,1'-spirobiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX
100mg
$ 243.00

Strem Chemicals
(S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,2,3,3-tetrahydro-1,1'-spirobiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX
25mg
$ 82.00

ChemScene
(Sa,S)-Ph-Bn-SIPHOX ≥97.0%
50mg
$ 245.00

ChemScene
(Sa,S)-Ph-Bn-SIPHOX ≥97.0%
25mg
$ 130.00

AK Scientific
(Sa,S)-Ph-Bn-SIPHOX
50mg
$ 628.40

Total 13 raw suppliers

Chemical Property of (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX

Chemical Property:

Melting Point:164-166°C
Boiling Point:702.3±60.0 °C(Predicted)
PKA:4.60±0.70(Predicted)
PSA：35.18000
LogP:6.44700
Sensitive.:moisture sensitive

Purity/Quality:

97% ^*data from raw suppliers

(S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,2,3,3-tetrahydro-1,1'-spirobiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Technology Process of (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX

There total 5 articles about (S)-(-)-7-[4(S)-(Benzyl)oxazol-2-yl]-7-diphenylphosphino-2,23,3tetrahydro-1,1'-spiroiindane, min. 97% (Sa,S)-Ph-Bn-SIPHOX which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

: 913829-83-1
(S,S)-N-(1-hydroxymethyl-2-methylbenzyl)-7'-diphenylphosphino-1,1'-spirobiindane-7-carboxylamide

: 913829-88-6,2074610-05-0
(S,S)-7-[4-(benzyl)oxazol-2-yl]-7'-diphenylphosphinyl-1,1'-spirobiindane

Guidance literature:: With 4-(Methylamino)pyridine; methanesulfonyl chloride; triethylamine; In dichloromethane; at 0 - 20 ℃;
DOI:10.1021/ja063444p

Reference yield:

: 913829-75-1
(S)-7-diphenylphosphino-7'-carbomethoxy-1,1'-spirobiindane

: 913829-88-6,2074610-05-0
(S,S)-7-[4-(benzyl)oxazol-2-yl]-7'-diphenylphosphinyl-1,1'-spirobiindane

Guidance literature:: Multi-step reaction with 3 steps

1: 99 percent / aq. KOH / methanol / 100 °C

2: 95 percent / HOBt; DCC / tetrahydrofuran / 20 °C

3: 75 percent / Et₃N; 4-methylaminopyridine; MeSO₂Cl / CH₂Cl₂ / 0 - 20 °C

With 4-(Methylamino)pyridine; potassium hydroxide; benzotriazol-1-ol; methanesulfonyl chloride; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; methanol; dichloromethane;
DOI:10.1021/ja063444p

Reference yield:

: 913829-78-4
(S)-7-diphenylphosphino-7'-carboxy-1,1'-spirobiindane

: 913829-88-6,2074610-05-0
(S,S)-7-[4-(benzyl)oxazol-2-yl]-7'-diphenylphosphinyl-1,1'-spirobiindane

Guidance literature:: Multi-step reaction with 2 steps

1: 95 percent / HOBt; DCC / tetrahydrofuran / 20 °C

2: 75 percent / Et₃N; 4-methylaminopyridine; MeSO₂Cl / CH₂Cl₂ / 0 - 20 °C

With 4-(Methylamino)pyridine; benzotriazol-1-ol; methanesulfonyl chloride; triethylamine; dicyclohexyl-carbodiimide; In tetrahydrofuran; dichloromethane;
DOI:10.1021/ja063444p