phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine)

Base Information

• Chemical Name: phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine)
• CAS No.: 857288-15-4
• Molecular Formula: C₂₇H₄₀NiOP₂
• Molecular Weight: 501.252
• Mol file: 857288-15-4.mol

Synonyms:

Chemical Property of phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine)

There total 2 articles about phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

trans-diphenyl-bis(trimethylphosphine)nickel(II) + Dicyclohexyl(2-hydroxyphenyl)phosphine (171364-77-5) → phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine) (857288-15-4)

Guidance literature:

In tetrahydrofuran; toluene; under dry, oxygen-free argon; a soln. of the organic ligand added to a stirred soln. of Ni-complex in THF/toluene; soln. heated to 60°C and stirred for 3 d; solvent removed in vacuum, and the residue washed with hexane; contaminated by a trace of Ph2Ni(PMe3)2; elem. anal.;

DOI:10.1002/zaac.200400435

Reference yield:

phenyllithium (591-51-5) → phenylnickel-2-(dicyclohexylphosphino)phenolate(O,P)(trimethylphosphine) (857288-15-4)

Guidance literature:

Multi-step reaction with 2 steps

1: tetrahydrofuran; diethyl ether

2: tetrahydrofuran; toluene

In tetrahydrofuran; diethyl ether; toluene;

DOI:10.1002/zaac.200400435

upstream raw materials:

Dicyclohexyl(2-hydroxyphenyl)phosphine

phenyllithium