dichlorotris[dimethyl(phenyl)phosphine]nitridorhenium(V)

Base Information

• Chemical Name: dichlorotris[dimethyl(phenyl)phosphine]nitridorhenium(V)
• CAS No.: 54192-79-9
• Molecular Formula: C₂₄H₃₃Cl₂NP₃Re
• Molecular Weight: 685.567

Synonyms:

Chemical Property of dichlorotris[dimethyl(phenyl)phosphine]nitridorhenium(V)

Chemical Property:

Purity/Quality:

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Technology Process of dichlorotris[dimethyl(phenyl)phosphine]nitridorhenium(V)

There total 3 articles about dichlorotris[dimethyl(phenyl)phosphine]nitridorhenium(V) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

tetrabutylammonium tetrachloronitridorhenate(VI) + Dimethyl(phenyl)phosphine (672-66-2) → dichloronitridotris(dimethylphenylphosphine)rhenium(V) (54192-79-9,25463-79-0)

Guidance literature:

In acetone; reflux (10 min); redn. of volume, addn. of Et2O, crystn. upon standing in a refrigerator,a 2nd crop is obtained from the mother-liquor;

DOI:10.1039/a705881k

Reference yield: 55.0%

[Re(NCO)Cl2(P(CH3)2(C6H5))3] (209392-68-7) → dichloronitridotris(dimethylphenylphosphine)rhenium(V) (54192-79-9,25463-79-0)

Guidance literature:

In toluene; byproducts: CO; Irradiation (UV/VIS); irradiation (N2 atm., 12 h, stirring, room temp.); concn. (vac.), evapn.;

DOI:10.1002/(SICI)1521-3749(199805)624:5<757::AID-ZAAC757>3.0.CO;2-B

Reference yield:

hydrazine dihydrochloride (14011-37-1,5341-61-7) + potassium perrhenate (10466-65-6) + Dimethyl(phenyl)phosphine (672-66-2) → dichlorotris[dimethyl(phenyl)phosphine]nitridorhenium(V) (25463-79-0,54192-79-9)

Guidance literature:

In ethanol; heating under reflux for 72 h; filtn., evapn. under low pressure, crystn. (ethanol);

DOI:10.1107/S0567740882010887

upstream raw materials:

Dimethyl(phenyl)phosphine

[Re(NCO)Cl₂(P(CH₃)2(C₆H₅))3]

hydrazine dihydrochloride

potassium perrhenate

Downstream raw materials:

{ReN(Cl)((CH₃)2C₆H₅P)2(S₂P(C₆H₅)2)}

{ReN(Cl)((CH₃)2C₆H₅P)2(O(C₂H₄)2NC(S)NC(NH)C₆H₅)}

{ReN(Cl)((CH₃)2C₆H₅P)2(C₅H₁₀NC(S)NC(NH)C₆H₅)}

{ReN(NCS)2(P(C₆H₅)(CH₃)2)3}

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