[(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)]

Base Information

• Chemical Name: [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)]
• CAS No.: 460718-11-0
• Molecular Formula: C₃₂H₃₂Co₂FeN₂OS₂
• Molecular Weight: 698.584
• Mol file: 460718-11-0.mol

Synonyms:

Chemical Property of [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)]

There total 2 articles about [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

{(Co(η-cyclopentadienyl))2(Fe(PPh3)(CO)2)(μ3-S)(η3-CS)} + 2-mesityl isocyanide (57116-96-8) → [(Co(η5-cyclopentadienyl))2(Fe(CO)2(CN(2,4,6-Me3C6H2)))(μ3-S)(μ3-CS)] (460718-08-5) + [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)] (460718-11-0) + (C5H5Co)2Fe(CNC6H2(CH3)3)3SCS

Guidance literature:

In dichloromethane; (N2); refluxing a soln. of cobalt complex with isonitrile in CH2Cl2 for 80 min, cooling; concn., chromy. (Al2O3, CH2Cl2/hexane), recrystn. (THF/hexane); elem. anal.;

DOI:10.1016/S0022-328X(02)01228-7

Reference yield: 25.0%

[(Co(η5-cyclopentadienyl))2(Fe(CO)(triphenylphosphine))(μ3-S)(μ3-C2S3)]*0.5(benzene) + 2-mesityl isocyanide (57116-96-8) → [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)] (460718-11-0) + [(Co(η5-cyclopentadienyl))2(Fe(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-C2S3)]

Guidance literature:

In dichloromethane; benzene; under N2; a soln. of FeCo2 complex and 2,4,6-trimethylphenylisocyanide in CH2Cl2 and benzene was heated under reflux for 2 min; chromy.; purifn. by crystn. from toluene/diethyl ether (Fe(CO)(CNMes)2-contg. compd.) and from THF/diethyl ether (Fe(CNMes)2-contg. compd.);

DOI:10.1039/b308320a

Reference yield: 60.0%

carbon disulfide (75-15-0,12122-00-8) + [(Co(η5-cyclopentadienyl))2(Fe(CO)(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-CS)] (460718-11-0) → [(Co(η5-cyclopentadienyl))2(Fe(CN(2,4,6-Me3C6H2))2)(μ3-S)(μ3-C2S3)]

Guidance literature:

In carbon disulfide; benzene; byproducts: CO; under N2; a soln. of FeCo2 complex in CS2 and benzene was heated under reflux for 2 h; solvent was removed under reduced pressure; residue was chromd. on alumina, a mixt. of CH2Cl2/hexane/THF eluted unreacted FeCo2 complex and a brown band from which a compd. was isolated; recrystn. from THF/diethyl ether; elem. anal.;

DOI:10.1039/b308320a

upstream raw materials:

2-mesityl isocyanide