2-ferrocenyl-4-methoxy-3-phenyl-2,4-cycloheptadienone

Base Information

• Chemical Name: 2-ferrocenyl-4-methoxy-3-phenyl-2,4-cycloheptadienone
• CAS No.: 933789-11-8
• Molecular Formula: C₂₄H₂₂FeO₂
• Molecular Weight: 398.284
• Mol file: 933789-11-8.mol

Synonyms:

Chemical Property of 2-ferrocenyl-4-methoxy-3-phenyl-2,4-cycloheptadienone

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of 2-ferrocenyl-4-methoxy-3-phenyl-2,4-cycloheptadienone

There total 1 articles about 2-ferrocenyl-4-methoxy-3-phenyl-2,4-cycloheptadienone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 72.0%

(2-phenylethynyl)ferrocene + pentacarbonyl[(cyclopropyl)methoxymethylene]molybdenum → 2-ferrocenyl-4-methoxy-3-phenyl-2,4-cycloheptadienone (933789-11-8) + 2-ferrocenyl-3-phenyl-2-cycloheptene-1,4-dione (933789-12-9)

Guidance literature:

In tetrahydrofuran; soln. of Mo complex (1 equiv.) and Fe complex (1.5 equiv.) in THF was refluxed under Ar; TLC monitoring; cooled to 25°C; solvent removed (vac.); chromd. (silica gel, hexane/EtOAc, 19/1 to 9/1);

DOI:10.1016/j.jorganchem.2006.12.008